用P507 萃取分离钴及草酸反萃制备草酸钴.pdfVIP

11 1 42 2 () Vol.42 No.2 2011 2 Journal of Central South University (Science and Technology) Feb. 2011 P507 ( 410083) P507 53.8 g/L () 25% P507+5% TBP+70%70%pH 3.510 min φ(O)/φ(A)1.5:1.03 99.5%4.9%3.1% P507 −2.043−0.812 1.586 kJ/mol 3 0.03 g /mL 40 φ(O)/φ(A)=1.0:2.5 99.5% P507 TG146.1 A 1672−7207(2011)02−0317−06 Extraction of cobalt with P507 and preparation of cobalt oxalate powders by ethane diacid stripping ZHANG Yang, MAN Rui-lin, WANG Hui, LIANG Yong-huang (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: The extraction and separation of Co, Ni and Li from Li-ion batteries powders leaching solution was carried out using P507, and cobalt oxalate was directly prepared by stripping with oxalic acid. The initial concentration of cobalt in feed solution was 53.8 g/L. The results show that the optimal extraction condition is as follows: organic phase composition of 25% P507+5% TBP+70% sulfonated kerosene; saponification rate is 70%, ambient temperature equilibration time is 10 min, phase ratio φ(O)/ φ(A) is 1.5:1.0 and aqueous phase pH is 3.5. In this condition, 99.5% of Co in the solution is extracted by three-stages extraction, while the extraction efficiency of Li and Ni is only 4.9% and 3.1%, respectively. The enthalpy of P507 extraction Co, Ni and Li is determined as −2.043, −0.812 and 1.586 kJ/mol, respectively. Oil, water and solid with good three-phase are separated by oxalic acid stripping. The optimum back