锰矿自还原压块高温还原过程中金属锰的挥发研究.docVIP

  Study on volatility of manganese metal in reduction process of manganese ore self-reduction pellets at high temperature# 5 10 15 20 25 30 XUE Zheng-liang, ZHANG Bo, YU Yue, DONG Jiang* (Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081,China) Abstract: In order to study the thermodynamic and kinetics of Mn volatilization in the reduction process, the self-reduction experiment of carbon-mixed manganese ore pellets was performed in carbon tube furnace at high temperature. The results show that the Mn equilibrium vapor pressure becomes higher and the Mn volatile quantity is increasing with the temperature increasing. A model, controlled by both the interface chemistry reaction and diffusion in solid products layer is established. The apparent activation energy of chemical reaction is 192.8kJ/moland the apparent activation energy of internal diffusion is 21.94kJ/mol, so the volatility of Mn is controlled by the chemical reaction rate. Key words: ferrous metallurgy;volatility of Mn; Mn self-reduction pellet; thermodynamic; kinetics 0 Introduction Since the beginning of 1990’s, the direct alloying technology of manganese ore used in converter has been studied [1~3]. Restrained by the imperfection of pretreatment of molten iron, large quantity of converter slag and so on, the economic benefit wasn’t satisfactory. Thereby, Xue Zhengliang and his colleagues proposed direct alloying of Mn self-reduction pellets in combined blown converter [4]. However, because Mn is volatile at high temperature, the manganese yield in molten steel has been lowered. Therefore, the study on the evaporation characteristics and rules of manganese metal in the reduction process of Mn self-reduction pellets is very important. 1 Experimental Method The raw manganese ore crushed into 10mm in diameter is heated to 1273K, and then kept on for 60min in the atmosphere of N2 to fully decompose crystal w