水体溶解性有机物(DOM)的分离提取与表征.docVIP

  水体溶解性有机物(DOM)的分离提取与表 征# 赵向阳1，王剑斌2，欧阳永炬2，杨欣2** 5 10 15 20 25 30 35 40 （1. 佛山市水业集团有限公司； 2. 中山大学环境科学与工程学院） 摘要：天然有机质（NOM）是消毒过程中形成具有致癌作用消毒副产物的主要前体物质。 但不同水体 NOM 各组分的复杂性致使对 NOM 特征的研究在水处理工艺中 DBPs 的控制有 重要意义。本实验以 Leenheer 的树脂联用分离富集 NOM 的方法，采用 XAD-8 离子交换树 脂和 MSC（H）阳离子交换树脂对广东省四处水样中的天然有机物(NOM)进行了提取和分 离。然后各组分分别进行 TOC、UV254 以及荧光检测等指标的检测，最后进行数据处理以 及结果的分析讨论，以此对所取水样中 NOM 及其各分离组分特性进行了比较和表征。本实 验研究结论主要如下：（1）亲水性组分是水样出水的主要成分，四个水样中都以小分子量 有机物为主要成分；（2）金沙洲、罗岗和沙口水样在微生物产物（SMPs）区域有比较明显 的吸收峰，罗岗水样在类腐殖质区域、金沙洲和竹料镇水样在简单芳香类蛋白质区域有明显 的吸收峰；（3）水样中腐殖酸类物质含量较少，而溶解性微生物产物和芳香性蛋白质含量 较高，亲水性碱性组分是主要的类腐殖质组分；溶解性微生物产物主要集中在亲水性组分 中 。 关键词：溶解性有机物； 树脂吸附； 提取分离； 表征 中图分类号：X522 Isolation and characterization of dissolved organic matter ZHAO Xiangyang1, WANG Jianbin2, OUYANG Yongju2, YANG Xin2 (1. Foshan Water Group; 2. School of Environmental Science and Engineering, Sun Yat-sen University) Abstract: DOM is major precursor disinfection byproducts. However, DOM is hard to be characterized due to its complex property and unpredictable variation in waters. Based on Leenheer’s comprehensive approach of isolation and fractionation of DOM from waters,we applied amberlite XAD-8 Resin and MSC(H) Resin to isolate complex mixtures of organic solutes from different waters into five groups. Waters sampled from the Zhuliao Street，Jinshazhou Bridge, The New Port of Luogang, as well as the Water plant of Shakou water treatment plant were examined, utilizing TOC, UV absorption and fluorescence spectroscopy in this test. The major results are (1) hydrophilic fractions and low moleculoar weight fractions occupies the biggest percenge of total DOC; (2) Water collected from Jinshazhou Bridge, the New Port of Luogang, the Water plant of Shakou sewage treatment plant had higher concentration of soluble microbial products (SMPs) than the other ones；(3) The amount of humic substances in sampled waters were less than aromatic proteins or SMPs, which were mainly occur in hydrophilic fractions. Key words: Dissolved organic matter (DOM); Resin ad