天津市松针中全氟化合物可挥发前体物的分布测定.docVIP

  天津市松针中全氟化合物可挥发前体物的 分布测定#  赵洋洋，姚义鸣，孙红文  ** 5 10 15 20 25 30 35 40 45 （南开大学环境科学与工程学院，教育部环境污染过程与基准教育部重点实验室，天津 300071） 摘要：全氟化合物（PFCs）广泛分布于环境各个介质中，其作为一类新型持久性环境污染物近年来备受关 注。而松针作为一种植物被动采样器曾应用于指示空气中多环芳烃、多氯联苯等憎水性有机污染物的水平。 本研究调查了天津市松针中 PFCs 前体物质的浓度水平，旨在探讨松针作为 PFCs 前体物天然被动采样装置 的可行性。结果表明，松针中 PFCs 前体物的总浓度范围为 0.03-5.94 ng/g（干重），平均浓度 0.55 ng/g （干重），不同采样点前体物的浓度水平存在差异。对于单个前体物，8:2 氟调醇的检出率高达 85%，浓度 在 0.03-2.27 ng/g （干重）之间，10:2 氟调醇全部被检出，浓度范围为 0.03-3.67 ng/g（干重）；N-乙 基全氟辛烷磺酰胺和 N-乙基全氟辛烷磺酰胺基乙醇的检出率较低；而 N-甲基全氟辛烷磺酰胺基乙醇和 6:2 氟调醇在松针中并未检出。松针中氟调醇的浓度水平随着碳链长度增加而增加。不同松针中前体物的总浓 度水平不同，油松中最高，圆柏次之，青海云杉和雪松中的总浓度水平较低，但相差不大。松针可作为被 动采样的一种形式，从一定程度上反映大气中 PFCs 前体物的浓度水平。 关键词：PFCs 前体；氟调醇；松针；被动采样技术 中图分类号：X511 The Distribution of Volatile Precursors of Perfluorinated Compounds in Pine Needles of Tianjin Zhao Yangyang, Yao Yiming, Sun Hongwen (College of Environmental Science and Engineering, Nankai University, Key Laboratory of Environmental Pollution Process and Standard (Nankai University), Ministry of Education, Tianjin 300071) Abstract: Perfluorinated compounds (PFCs) are ubiquitous in environmental media. As a new type of persistent organic pollutants (POPs), they have drawn much scientific attention in recent years. Pine needles, a commonly used passive air sampler, have been reported to be an indicator of atmospheric contamination levels of hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl (PCBs). In the present study, the levels of PFC precursors were detected in pine needles of Tianjin to check their applicability in monitoring this kind of new POPs. The results showed that the concentrations of PFC precursors ranged from 0.03to5.94 ng/g (dw), with the average concentration being 0.55 ng/g (dw). The PFCs precursors’ levels varied among different sampling sites. As to single precursor, N-methyl perfluorooctane sulfonamidoethanol and 6:2 fluorotelomer alcohol (6:2 FTOH) were not detected, and the detection rates of N-ethyl perfluorooctane sulfona