固相萃取-双柱气相色谱法测定水中多种有机磷农药残留.pdfVIP

第37卷第5期 中国测试 Vo1．37 No．5 2011年 9月 CHINA MEASUREMENT TEST September。2011 固相萃取一双柱气相色谱法测定水中 多种有机磷农药残留 陈 烨，许秀艳，吕怡兵，滕恩江，邢冠华 ，王 超 (中国环境监测总站，北京 1ooo12) 摘 要：针对单一气相色谱柱定性分析易出现假阳性误判的情况，采用固相萃取一气相色谱双柱技术测定环境水体中 多种有机磷农药的残留量。水样中的有机磷农药通过HLB固相萃取小柱富集，经洗脱浓缩后，用DB-35MS和HP-5 毛细管气相色谱柱、火焰光度检测器测定。方法的平均加标回收率为86．1％一118％，相对标准偏差为3．2％-6．8％，最 低检出限为20—40ng，L，可满足环境水体中痕量有机磷农药残留的分析需要。 关键词：有机磷农药；固相萃取；气相色谱；双柱；水 中图分类号：0562．3+2；TQ453．2+2 文献标志码：A 文章编号：1674—5124(2011)05-0053-03 Determination ofmultipleorganophosphorouspesticideresiduesin waterby dual-column gaschromatography coupled with solid phaseextraction CHENYe，XUXiu—yan，Li3Yi—bing，TENGEn-jiang，XINGGuan-hua，WANGChao (ChinaNationalEnvironmentalMonitoringCentre，Beijing100012，China) Abstract：Toavoid the caseoffalsepositive when analyzing by singlecolumn，thedual-column gas chromatography coupled with solid phase extraction was applied to the multi-residue determination of organophosphorous pesticides in environmental water． rhe organophosphorous pesticideswere extracted from waterwith HLB solid phase extraction cartridgesand then eluted． Afterconcentrated．theeluentswere detected by GC—FPD with DB-35MS and HP-5 capillary columns．The average recoveries of5 replicatesforanalytesranged from 86．1％ to l18％ ．with relativestandard deviationsbetween 3．2％ and 6．8％．And themethod detection limitswerewithin the range of20ng／L to 40ng／L．The results showed thattheproposed method is suitable forthe detemr ination oftrace amountsofmultiple organophosphorouspesticide residues in environmental warer． Keywords：organophosphorouspesticides；solid-phaseextraction；gaschromatography；dual-column； warer O 引 言 用和