几种羧酸聚合物阻垢剂阻垢作用的匹配模型.pdfVIP

《化学通报》在线预览版 几种羧酸聚合物阻垢剂阻垢作用的匹配模型 夏明珠 王风云 雷武 （南京理工大学化工学院 南京 210094 ） 摘要 实验室采用静态阻垢法评定了水解聚马来酸酐(HPMA)、聚丙烯酸(PAA)、丙烯酸-丙烯酸羟丙酯共聚物(T-225)、 丙烯酸-2-丙烯酰氨基-2- 甲基丙基磺酸共聚物(AA-AMPS) 以及膦酰基羧酸调聚物(POCA)对碳酸钙和硫酸钙的阻垢 性能，发现对碳酸钙的阻垢作用依次为 HRMAPAA ，T-225POCA，AA-AMPS 。对于CaSO4 的阻，POCA 和 AA-AMPS 在低浓度时就表现出良好的抑制作用，性能最好，其次是 T-225，当加药量大于 10mg/L 后 HPMA 的性能与T-225 相当， PAA 的性能相对稍差。通过半经验PM3 方法计算了这几种聚合物的构型及相关参数，发现聚合物中某些功能基团的空间 距离与垢晶面阳离子间距相匹配，与垢晶面阳离子间距相匹配的功能基团数目的不同，显示出阻垢性能的差异。理论计 算结果与实验结果一致。 关键词 羧酸聚合物 阻垢 吸附 匹配 The Match Model of Scale Inhibition of Some Carboxylic Acid Polymers Xia Mingzhu, Wang Fengyun, Lei Wu (The Institute of Chemistry Technology, Nanjing University of Science Technology, Nanjing 210094) Abstract The performance of scale inhibition of hydrolyzed polymaleic anhydride(HPMA) 、PAA(polyacrylic acid) 、 T-225(acrylic acid-hydroxypropyl acrylate copolymers) 、acrylic acid-2-acrylamido-2-methylpropanesulfonic acid copolymer (AA-AMPS copolymer) and phosphono carboxylic acid telomer (POCA) on CaCO3 and CaSO4 was studied by static scale-inhibiting method, the result shows the performance of scale inhibition on CaCO3 is order of HPMA, PAA and T-225, POCA and AA-AMPS copolymers. The effect of scale inhibition of POCA and AA-AMPS copolymer at low concentration on CaSO4 is good, T-225 is less stronger and HPMA is correspond to T-225 when its concentration is higher than 10 mg/L, the last is PAA. The structure and corresponding parameters of polymers were calculated by semi-empirical PM3 method, it shows that the space distance of some functional groups in polymer matchs with cation distance of scale crystal surfaces, the d