采用联用技术测定中国海产品中砷的形态_英文_.pdfVIP

第22 卷 第3 期 环 境 化 学 Vol. 22, No. 3 2003 年 5 月 ENVIRONMENTAL CHEMISTRY May 2003 ARSENIC SPECIATION IN CHINESE SEAFOODS BY USING HYPHENATED TECHNIQUES1) WEI Chao LI Wei2hua ZHANG Chao ZHANG Xin2rong2) (Department of C emistry, Tsing ua University, Beijing, 100084) VAN H ULLE Marjin CORNELIS Rita (Laboratory ofAnalytical Sciences, G ent University, Proeftuinstraat, 86, 9000, Gent, Belgium) Abstr act A study was carried out to determine arsenic species in seafood samples collected from C inese sea. T e information about arsenic species in samples was provided by ig performance liquid c ro2 matograp y- inductively coupled plasma2mass spectrometer (HPLC2ICP2MS) and electrospray tandem mass spectrometry (ES2MS2MS) . T e arsenic species in t irty C inese edible seafoods, including algae, fis , crab, s rimp, mussels, oysters, and clams popularly ingested by C inese people as regular foods, were examined in t e present report. Arsenosugars were detected in all of t e extracted algae samples ( 115) 3318Lg# g- 1 dry weig t) and some s ellfis samples (01018) 0178Lg# g- 1 wet weig t) . Arseno2 betaine was detected in all of t e extracted fis and s ellfis samples ( 01025) 61604Lg# g- 1 wet weig t) . In contrast, inorganic arsenic was only present in t e examined fis and s ellfis samples, at levels less t an 2% of t e total arsenic. T e study provides information about a possible distribution pat2 tern of arsenic species in seafood products. Keywor ds arsenic, seafood, HPLC2ICP2MS, ES2MS2MS. 1 Intr oduct ion