Co-Mo-B非晶态催化剂的制备、表征和加氢脱氧性能研究.pdfVIP

Co–Mo–B 非晶态催化剂的制备、表征及加氢脱氧性能研究 王威燕，杨运泉，罗和安，刘文英，胡韬 （湘潭大学化工学院，湖南湘潭 411105 ） 摘要：以NaBH4 作为还原剂，采用化学还原法制备出Co-Mo-B 非晶态催化剂，用BET ，SEM， XRD ，ICP 和XPS 对催化剂进行表征分析，以苯酚为模型化合物研究其加氢脱氧性能。并研究了 催化剂的制备时间对催化剂加氢脱氧活性的影响。结果表明，Co-Mo-B 非晶态催化剂具有很好的 热稳定性，制备时间并不影响催化剂的非晶态结构，催化剂颗粒粒径随着制备时间的延长而逐渐 增大。在催化苯酚的加氢脱氧反应中，苯酚的加氢脱氧反应路径主要按先加氢在脱氧的方式进行。 影响催化剂催化活性的主要因素是催化剂表面能提供的自由氢量和催化剂表面 Brönsted 酸中心 4+ Mo 的含量。在548 K，氢压4.0 MP 时，苯酚的转化率高达100%，脱氧选择性达99.6% 。产物 主要为环己烷，其中芳烃含量降低至1.8%，H/C 原子比达到1.98。 关键词：加氢脱氧；Co–Mo–B 非晶态催化剂；苯酚；芳烃含量；生物油 中图分类号：TQ 028.8 文献标识码：A Preparation, characterization and hydrodeoxygenation properties of Co–Mo–B amorphous catalyst Weiyan Wang, Yunquan Yang, Hean Luo, Tao Hu, Wenying Liu （School of Chemical Engineering，Xiangtan University ，Xiangtan 411105 ，Hunan ，China ） Abstract: Co–Mo–B amorphous catalysts were prepared by chemical reduction method and characterized by BET, SEM, XRD, ICP and XPS. The hydrodeoxygenation (HDO) properties of these catalysts were tested using phenol as the model compound. The result showed that Co–Mo–B amorphous catalysts had good thermal stability and the catalyst preparation time had no influence to their amorphous structure but great effect on the catalyst surface composition and their HDO activity. The main reaction route in the HDO of phenol on Co–Mo–B amorphous catalyst proceeded with hydrogenation–dehydration rather than direct hydrogenolysis. The main factors which influenced the catalyst activity were the sufficient supply of free hydrogen and the high content of Mo4+ Brönsted acid on catalyst surface. The phenol conversion was high to 100% with a deoxygenation selectivity 99.6% at 548 K. The aromatics content in the products was decreased to 1.8% and the H/C atom ratio was incre