金红石型纳米TiO2和有机紫外吸收剂对聚丙烯酸酯抗老化性的影响.pdfVIP

金红石型纳米TiO 和有机紫外吸收剂对聚丙烯酸酯 2 抗老化性的影响 么秋香 杜美利 西安科技大学 化学与化工学院，陕西 西安 710054 摘要：利用紫外-可见吸收光谱研究了金红石型纳米 TiO 、有机紫外吸收剂UV-531 相 2 互复配后的紫外- 可见吸收光谱图；采用超声分散和原位聚合两种方法将复配的 R-TiO2/UV-531 纳米复合紫外光吸收剂添加到聚丙烯酸酯乳液中，对其涂膜进行人工加 速老化实验。通过FTIR 、DT-TG 和SEM，研究了R-TiO2/UV-531 对聚丙烯酸酯乳液抗 老化性能的影响。结果表明：无机和有机紫外吸收剂的复配拓展了紫外光区的吸收范围， 优于单一的无机/有机紫外吸收剂，表现出协同增效作用。纳米R-TiO2 对聚丙烯酸酯涂 膜的紫外老化起到了减缓作用，而原位聚合使R-TiO2/UV-531 更好的分散于乳液中，提 高了其抗紫外老化性。 关键字：聚丙烯酸酯乳液；纳米R-TiO2 ；UV-531 ；原位聚合 中图分类号：TQ630.4 文献标识码：A Effects of Nano-rutile TiO and Organic UV Absorbers on 2 the Anti-aging of Polyacrylate YAO Qiuxiang DU Meili (Institute of Chemistry and Chemical Engineering ，Xi’an University of Science and Technology，Xi’an 710054 ，Shanxi ，China) Abstract ：UV-Vis spectrum of nano-rutile TiO2, UV-531 and hybrid ultraviolet absorbents were studied. Polyacrylate emulsion with hybrid ultraviolet absorbents was prepared vis ultrasonic blending method and in-situ polymerization. Their structure and properties were characterized using FTIR, DT-TG and SEM. And the effects of anti-aging in system of polyacrylate emulsion were investigated. The results show that organic-inorganic hybrids expand the range of ultraviolet absorption and have better performance of ultraviolet absorption with synergistic effects than organic/inorganic only. Nano-rutile TiO2 slow down the ultraviolet anging of coatings while R-TiO2/UV-531 improve it much better by in-situ polymerization. Keywords ：polyacrylate emulsion ；nano-rutile TiO2 ；UV-531 ；in-situ polymerization 联系人：杜美利. 第一作者：么秋香（1983-），女， Corresponding author: Prof. DU Meili. E-mail: 西安科技大