卷烟烟气中亚硝胺测定方法的研究.pdfVIP

卷烟烟气中亚硝胺测定方法研究 谢复炜赵明月 金永明刘克建张龙根李萍 【关键词】卷烟烟气；总粒相物；烟草特有N一亚硝胺；GC—TEA；GC—NPD；TSNAs 【摘要】本项研究对现有的TSNAs的收集分析方法进行了全面评价，优化了前处理过程及仪器分析 条件．建立了使用经抗坏血酸处理的玻璃纤维滤片收集卷烟烟气总粒相物，用二氯甲烷萃取粒相物 稳定性和重复性好、准确性和精确度高。对国内外较有代表性的98种卷烟样品中的TSNAs进行了 系统的分析测定。分析结果表明：混合型卷烟烟气中TSNAs的含量显著高于烤烟型卷烟烟气中 TSNAs，国外混合型卷烟中NNK的含量高于国内混合型卷烟。在卷烟配方中减少晾晒烟用量可以显 著降低TSNAs的水平。这些研究结果为制定我国卷烟烟气中TSNAs含量限量标准、建立技术壁垒提 供了可靠的技术基础。 in and determinationof nitrosamines 【Abstract】Twomethods，GC—NPDGC-TEA，for tobacco—specific forTSNAs becauseofremarkable smokewerestudied．GC-NPDwasfoundnotsuitable analysis cigarette interference．Themethodto TSNAsin smokewithGC—TEAwas quantify cigarette optimized．Theprocedure involved mainstreamsmokeona filtertreatedwithasolutionofascorbic trapping Cambridge acid，extraction ofTSNAsfromthefilterwith thediehloromethaneand onabasic dichloromethane，evaporatingclean—up alumina column．Thewas chromatographysampleanalyzed“tllgaschromatography／thermalenergyanalyzer and aninternalstandard werelinearandrecoveriesweremorethan quantifiedby procedure．Allresponses of mole ofTSNAsin 87％．Themethodwas and than determining simple，precisecapable lng／cig cigarette smoke．The98kindsofdomesticand were inthis resultsindicatedthat foreigncigarettesanalyzedstudy．The theTSNAs inmainstreamsmokeofAmerican—blendedaremuch thanthoseof yields cigarettes highcr flue-cured andtheNNK inmainstreamsmokeof blended are than cigarettes