乙烯燃烧简化化学动力学模型和其验证.pdfVIP

23 2 Vol.23,No.2 2009 06 Journal of Experiments in Fluid Mechanics Jun., 2009 :2009) 1, 2 2 2 杨顺华 , 肖保国 ,钱炜祺 ( 1. , 230026; , 621000) : , , 20 16 , O Ar 2 , :,; , :; ;;; :O354.4 : A Reduced chemical kinetics and test for ethylene combustion 1, 2 2 2 YANG Shunhua , IAO Baoguo , QIAN Weiqi ( 1.Department of Modern Mechanics,University of Science and Technology of China,Hefei 230026, China; 2.China Aerodynamics Research and Development Center,Mianyang Sichuan 621000, China) Abstract: A reduced chemical kinetics including 20 species and 16 global reactions was obtained by re ducing the detailed kinetics for ethylene combustion with themethod of quasisteady state approximation (QS SA) .Experimental measurements of a laminar premixed ethyleneO2Ar flamewere carried out on the combus tion station at National Synchrotron Radiation Laboratory (NSRL) to validatethe kinetics.Onedimensional nu merical methodwas implemented to simulatethetest.Comparison with each other shows that thereduced kinet ics has the ability to represent efficiently thereaction mechanisms of detailed element reaction model.Some dif ference between the experimental data and calculated results with detailed kinetics indicates the modifications of the detailed kinetics is needed. Key words: ethylene; quasisteady state approximation (QSSA) ; reduced chemical kinetics; synchrotron radiation photo ionization;combustion 0 ,( , ) ,