新型无磷缓蚀剂在强腐蚀性水中对碳钢的缓蚀作用.pdfVIP

The 6th China Corrosion Conference Inhibition Action of a New Fatty Amide Derivative Inhibitor on Carbon Steel in Corrosive Water Lei TAO, Shuzhong ZHENG, Jun CHEN, Chao WANG, Lijuan QIN CNOOC Tianjin Research and Design Institute of Chemical Industry, Tianjin, China, 300131 Email :pao992@163.com Abstract: A new “green” corrosion inhibitor named N-alkyl-N-fatty acylamino fatty acid salt (NAFAS) was synthesized and characterized. The corrosion inhibition performance of NAFAS on carbon steel in corrosive circulation cooling water with low alkalinity, low hardness and high chlorine ion concentration was studied by polarization curves, electrochemical impedance spectroscopy (EIS). The results show that the new fatty amide derivative inhibitor NAFAS was a good corrosion inhibitor for carbon steel, which behaved as a type of anodic inhibitor. The inhibition efficiency increases with an increase in the NAFAS concentration. NAFAS is adsorbed on the steel surface according to Langmuir isotherm adsorption model. Keywords: corrosion inhibitor; low carbon steel; circulation cooling water; polarization curves; electro- chemical impedance spectroscopy (EIS) 新型无磷缓蚀剂在强腐蚀性水中对碳钢的缓蚀作用 陶蕾，郑书忠，陈军，王超，秦立娟 中海油天津化工研究设计院，天津，300131 Email: pao992@163.com 摘 要：开发了一种新型环境友好型脂肪酰胺类无磷缓蚀剂（NAFAS ）。采用极化曲线和电化学阻 抗谱方法研究了NAFAS 对碳钢在低碱低硬高氯离子浓度的循环冷却水中的缓蚀性能。研究结果表明： NAFAS 缓蚀剂在具有强腐蚀性的海水淡化水中表现出良好的抑制腐蚀效果；其缓蚀效率随着缓蚀剂 浓度的增大而增大。等温等压条件下，无磷缓蚀剂能自发地吸附在碳钢表面。其在金属表面的吸附服 从Langmuir 单分子层吸附模型。 关键词：缓蚀剂；碳钢；循环冷却水；动电位极化；电化学阻抗谱 1 引言 2.1 试样及实验介质的准备 2