直接还原熔分渣制备富钛料实验室研究.pdfVIP

·118· 张树立：直接还原熔分渣制备富钛料实验室研究 中国攀枝花 直接还原熔分渣制备富钛料实验室研究 张树立 （攀枝花学院） 摘 要：熔分渣是钒钛磁铁矿经转底炉直接还原—电炉熔分而得到的副产品，其TiO2 含量为~50% ，不宜 直接作为氯化法钛白和海绵钛生产的原料。本文采取湿法处理工艺，对熔分渣杂质去除和 TiO2 富集进行 了实验研究，包括 HCl 和 HF 酸浸、高压 HCl 浸出及钠化焙烧—酸浸等工艺路线的探讨，以期生产出能 满足工业生产的富钛料。通过试验研究表明，钠化焙烧—酸浸工艺所得到的 TiO2 品位最高，达到70.45%， 最佳工艺参数为：焙烧温度 600℃，焙烧时间 2h ，渣碱比为 0.99，盐酸浓度 9%，液固比 9:1，反应时间 3h，反应温度 80℃。 关键词：熔分渣；钠化焙烧；高压酸浸 Laboratory Studies on Preparation of Rich Titanium Concentrate by Molten-separated Slag Produced by Direct Reduction Process Zhang Shuli (Panzhihua University,Panzhihua 617000,Sichuan,China) Abstract: Molten-separated slag is a by-product produced by direct reduction process- molten separation process using with vanadium-titanium magnetite, which contains about 50% of TiO2 and is unsuitable to be used as raw materials to produce titanium dioxide by chloride process and titanium sponge.This article studied the removal of the impurities and the enrichment of titanium dioxide in molten-separated slag by the wet process, including the HCl and HF acid leaching procee, the high-pressure HCl leaching process and the sodium roasting-acid leaching process in the hope of producing the titanium-rich material which fulfilled the demands of industry. The experiment results show that the highest grade of TiO2 is 70.45% producing by the sodium roasting-acid leaching process. The optimal technical parameters are as follow: the calcination temperature: 600°C, the calcination time:2h, the ratio of slag and alkali:0.99, the concentration of