混煤热解反应动力学特性研究.pdfVIP

27 卷 17 期 中 国 电 机 工 程 学 报 Vol.27 No.17 Jun. 2007 2007 年6 月 Proceedings of the CSEE 2007 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2007) 17-0006-05 中图分类号：TK229 文献标识码：A 学科分类号：47010 混煤热解反应动力学特性研究 平传娟，周俊虎，程 军，杨卫娟，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Research on the Pyrolysis Kinetics of Blended Coals PING Chuan-juan, ZHOU Jun-hu, CHENG Jun, YANG Wei-juan, CEN Ke-fa (State Key Laboratory of Clean Energy Utilization (Zheji ang University), Hangzhou 310027, Zheji ang Province, China) ABSTRACT: Coats-Redfern integral method was used to [1] 要的意义 。热解的研究通常从动力学特性入手来 obtain the kinetics of the complex devolatilisation process. 解释其过程的发展，获得化学反应的速度及进度。 Anthracite and bituminous-coal and their binary blends were 从应用角度看，动力学计算的目的是为了获得相对 devolatilised at low heating rate in a thermo-gravimetric 简单的模型用于指导设计和实际操作运行；而从理 analyzer. At the whole active pyrolysis stage, anthracite has a 论上讲，尽管热解过程由许多复杂反应构成，但随 lower apparent active energy than bituminous-coal, which was 着反应的进行，一些机制性的变化过程还是会以宏 variance with pyrolysis reactivity. The pyrolysis mechanism is [2] 观反应动力学 的方式表现出来。 varied in different stage; the kinetic parameter is the average 热分析法具有试样量少、速度快并且能在测量 value. By subsection analysis, the one-way transport diffusion 温度范围内研究原料受热发生热反应的全过程等 model was adapted to lower temperature range and the third