稀土铕配合物光致变色材料合成及光谱测定方法.pdfVIP

Synthesis of Rare Earth Europium Complex Photochromic Materials and Its Spectrometric Methods Hao Xiaoxiu1,2, Sun Cheng1,2, Meng Jie1,2 ,Yang Shuhui2 （1、Tianjin Vocational Institute, Tianjin, 300402; 2、Tianjin University of science and technology, Tianjin, 300222 ） Abstract: Light-emitting of rare earth europium complex photochromic material is an interdisciplinary study of inorganic and organic light-emitting. It has great research significance both in theory and application. In this paper, ternary rare earth europium complexes are synthesized, including the option of ligands, the optimal ratio of ligand and rare earth, the option of catalysts, influence of different optimal ratio on intensity and stability of rare earth complexes and so on. By using fluorescent spectrum, the falsification-resistant property of ternary-rare earth europium complexes is evaluated. This study has some guiding sense over the application and production of rare earth europium complex photochromic materials in falsification-resistant ink and paper counterfeiting field. Key words: synthesis of rare earth europium complex, photochromic materials, fluorescent spectrum 稀土铕配合物光致变色材料合成及其光谱测定方法 1,2 1,2 1,2 2 郝晓秀 孙诚 孟婕 杨淑蕙 1.天津职业大学，天津，中国 300410；2.天津科技大学，天津，中国 300222 e-mail: haoxx888@ 【摘要】稀土有机配合物发光是无机发光和有机发光研究的交叉学科，有着重要的理论研究意义及实 际应用研究价值。本论文对光致变色三元稀土铕配合物的合成进行了研究，包括对配体种类的选择、 稀土与各配体的最佳比例确定、催化剂选择、不同配体比例对稀土配合物强度的影响以及配合物的稳 定性等进行研究，并利用荧光光谱图定量测定了稀土配合物光致变色材料的防伪性能,对稀土配合物光 致变色材料在油墨以及纸张防伪领域的应用和生产具有一定的指导意义。 【关键词】稀土配合物合成，光致变色材料，荧光光谱 应。稀土配合物的发光过程是配合物中的有机配体 引言 吸收紫外光，