The effect of zeolite particle size on the activity of MoHZSM-5 in non-oxidative methane dehydroaromatization外文翻译.pdfVIP

Applied Catalysis A: General 393 (2011) 348–358 Contents lists available at ScienceDirect Applied Catalysis A: General j o u rn al h omepage: w w w. elsev /locate/apc ata The effect of zeolite particle size on the activity of Mo/HZSM-5 in non-oxidative methane dehydroaromatization Yanbin Cui, Yuebing Xu, Jiangyin Lu, Yoshizo Suzuki, Zhan-Guo Zhang ∗ National Institute of Advanced Industrial Science and Technology (AIST), Onogawa 16-1, Tsukuba 305-8569, Japan a r t i c l e i n f o a b s t r a c t Article history: The effect of the particle size of HZSM-5 on the activity of Mo/HZSM-5 in the non-oxidative CH4 dehy- Received 24 June 2010 droaromatization was studied. For the purpose five 5 wt%Mo/HZSM-5 catalysts based on one highly Received in revised form 9 December 2010 crystalline parent HZSM-5 of an average particle size of 4 m and four ball-milled samples with their Accepted 10 December 2010 average particle sizes being 1.9, 1.0, 0.5 and 0.2 m, respectively, were prepared using conventional Available online 16 December 2010 impregnation method, characterized using XRD, BET, 27Al MAS NMR, NH -TPD, H -TPD, TPO and TG tech- 3 2 niques, and tested at 1073 K and a wide range of space velocities from 5000 to 20,000 ml/h/g. XRD and Ke