水蒸气及氧气复合气氛对活性半焦孔隙结构演化的影响.pdfVIP

第 21 卷 第 4 期 燃 烧 科 学 与 技 术 Vol.21 No.4 2015 年 8 月 Journal of Combustion Science and Technology Aug. 2015 DOI 10.11715/rskxjs.R201503037 水蒸气及氧气复合气氛对活性半焦孔隙结构演化的影响 张 振，王 涛，冯 太，马春元 (山东大学燃煤污染物减排国家工程实验室，济南 250061) 摘 要 ：采用烟煤为原料，在沉降炉试验台上研究快速加热条件下，水蒸气和氧气复合气氛对活性半焦孔隙结构的 影响．通过氮气吸附、骤冷固体密度泛函方法研究活性半焦孔隙结构的演化，通过扫描电镜的方法研究活性半焦的 表面烧蚀特性．结果表明，活性半焦的低吸附等温线的类型具备Ⅰ型和Ⅳ型等温线的特征．一定体积分数氧气与水 蒸气对孔隙结构发展都有促进作用．氧气与水蒸气在活性半焦制备过程中作用机理不同，氧气参与表面反应，水蒸 气参与孔隙中反应，氧气对表面烧蚀作用强． 关键词 ：活性半焦；孔容；微孔；氧气；水蒸气 中图分类号：TQ536.1 文献标志码 ：A 文章编号 ：1006-8740 (2015)04-0318-06 Influence of Steam and Oxygen on Pore Structure Evolution of Active Semi-Char Zhang Zhen ，Wang Tao ，Feng Tai ，Ma Chunyuan (National Engineering Laboratory of Coal-Fired Pollution Reduction ，Shandong University ，Jinan 250061 ，China) Abstract ：Bituminous coal was used to prepare activated char through fast pyrolysis process in a drop-tube reactor. The effect of oxygen concentration on pore structure was investigated. The evolution of pore structure was characterized by quenched solid density functional theory (QSDFT)method using nitrogen adsorption and the surface ablation by scanning electronic microscopy (SEM). The results indicate that the absorption isotherms of semi-char samples possess some fea- tures of isotherms of types Ⅰ and Ⅳ. Appropriate oxygen concentration and steam concentration are beneficial to the development of pore structure. The mechanism of oxygen and steam is different during the preparation