Vitamin B1 self-assembled monolayers modified gold electrode Dopamine and Uric Acid Catalysis_0.docVIP

 PAGE \* MERGEFORMAT 31 Vitamin B1 self-assembled monolayers modified gold electrode Dopamine and Uric Acid Catalysis [Abstract] of vitamin B1 (VB1) in the self-assembled on gold electrode was prepared VB1 self-assembled monolayer modified gold electrodes (VB1 Au / SAMs / CME). Preliminary studies by cyclic voltammetry of this modified self-assembled monolayers electrochemical behavior. The results show that: VB1 the gold electrode surface adsorption. to [Fe (CN) 6] 3 - / 4 - redox as a probe to investigate the VB1 self-assembled monolayer modified gold electrodes chemical properties, VB1 the presence of SAMs [Fe (CN) 6] 3-/4- electron transfer has a significant impediment. of the dopamine (DA) and uric acid (UA) in the behavior of this electrode . Experimental results show that, DA and UA in this electrode can be electro-catalytic oxidation. differential pulse voltammetry (DPV) peak current and DA concentration in the 2.0 × 10-5 ~ 4.0 × 10 4 mol / L range was line sexual relations, the linear range of determination of UA 6.0 × 10-5 ~ 2.2 × 10-4 mol / L, and can achieve the simultaneous determination of these two substances. [Keywords:] Vitamin B1, self-assembly, dopamine, uric acid, electrocatalysis, chemically modified electrode Abstract Vitamin B1 self assembled monolayer modified electrode (VB1 Au / SAMs / CME) was prepared and its electrochemical behavior was studied by cyclic voltammetry. The results showed that a self assembled monolayer (SAM) was formed on the surface of gold electrode. [Fe (CN) 6] 3-/4-redox couple was used as the electrochemical probe to study the electrochemical characteristics of SAM modified gold electrode and the results indicated that the existence of Vitamin B1 membrane on gold surface hindered the electron transfer. The electrochemical behaviors of dopamine (DA) and uric acid (UA) were investigated at VB1 Au / SAMs / CME. The results showed that the electrochemical oxidation of DA and UA could be electrocatalyzed. Ther