水热法制备8YSZ纳米粉体及其烧结活性的研究.docVIP

Hans Journal of Nanotechnology纳米技术, 2011, 1, 6-11 /10.12677/nat.2011.11002 Published Online May 2011 (/journal/nat/) Hydrothermal Synthesis of 8YSZ Nanopowerders and Their Sinterabilities Baoan Fan , Jiabao Yan, Jianghua Qiu, Xiaochao Yan * Key Laboratory of Coal Conversion and New Carbon Materials, Hubei Province, Wuhan University of Science and Technology, Wuhan Email: fanbaoan@ Received: Mar.22nd, 2011; revised: Apr.12th, 2011; accepted: Apr.13th, 2011. Abstract: The cubic phase 8YSZ ([ZrO ] ·[Y O3]0.08)nanopowders were synthesized by a chemical 2 0.92 2 co-precipitation method combined with hydrothermal crystallization treatment. The average size of 8YSZ crystallines was in the range of 7 - 8 nm and they were softly congregated with the aggregation strength of only 20 MPa. The as-synthesized 8YSZ nanopowders exhibited high sinterabilities, and they started to rap- idly thermo shrink at 1000?C and reached the maximum shrinkage rate at 1065?C. At 1200?C, the shrinkage process was basically finished. When sintered at 1000?C for 8 hrs or 1100?C for 4 hrs, the block of 8YSZ nanopowders can be basically densified, whereas the block of 8YSZ nanopowders synthesized by water-and ethanol-washed can only be basically sintered to dense at 1300?C for 10 hrs. The high sinterabilities of hy- drothermal 8YSZ nanopowders are attributed to their fine crystalline size and incompact aggregation. Keywords: YSZ; Nanopowders; Hydrothermal Method; Sinterability 水热法制备 8YSZ纳米粉体及其烧结活性的研究 * 范宝安 ，颜家保，邱江华，颜晓潮 武汉科技大学，湖北省煤转化与新型炭材料重点实验室，武汉 Email: fanbaoan@ 收稿日期：2011年 3月 22日；修回日期：2011年 4月 12日；录用日期：2011年 4月 13日 摘 要：本文采用化学共沉淀结合水热晶化的方法，在 200?C 的温度下合成出了具有立方相的 8YSZ([ZrO ] ·[Y O3]0.08)纳米粉体，粉体的晶粒尺寸在 7~8 nm左右，粉体为软团聚，团聚体强度只有 2 0.92 2 20 MPa，粉体具有很高的烧结活性，1000?C下就开始了快速收缩，1065?C下收缩速率达到最快，1200?C 下收缩基本结束，块体材料 1000?C下保温 8 h或 1100?C下保温 4 h以后就基本上实现了致密化，相比 之下采用化学共沉淀结合水洗-醇洗-煅烧法需要在 1300?C烧结 10 h才能基本上实现致密化。水热晶化 法制备的 8YSZ纳米粉体的高烧结活