Aqueous-Phase Sorption Behaviors of Cs+, Co2+, Sr2+ and Cd2+ions on some Composite Ion Exchangers英文文献资料.docVIP

Advances in Chemical Engineering and Science, 2012, 2, 180-186 /10.4236/aces.2012.21021 Published Online January 2012 (http://www.SciRP.org/journal/aces) Aqueous-Phase Sorption Behaviors of Cs+, Co2+, Sr2+ and Cd2+ Ions on Some Composite Ion Exchangers Ibrahim Mohammed El-Naggar, Gehan Mohammed Ibrahim, Eman Ahmed El-Kady Hot Laboratories Center, Atomic Energy Authority, Cairo, Egypt Email: eman_nuclear@ Received November 18, 2011; revised December 25, 2011; accepted January 3, 2012 ABSTRACT A two new hybrid “organic-inorganic” composite ion exchangers (SAM and FAM), was synthesized by the combina- tion of inorganic ion exchanger tin (IV) silicate and tin (IV) antimonate respectively with organic polymer polyacryla- + 2+ 2+ 2+ mide (PAm). The sorption isotherms for Cs , Co , Sr and Cd ions on composite ion exchanger were investigated in the range (0.0005 - 0.01 M) at different reaction temperature (30?C, 45?C and 60?C ± 1?C). The sorption data were sub- jected to different sorption isotherms and the results verified that Langmuir isotherm is the best model to be applied, and the monolayer sorption capacity were calculated and was found to increase as the reaction temperature increases. Keywords: Organic-Inorganic Composite; Polyacrylamide; Tin (IV) Silicate; Tin (IV) Antimonate; Radioactive Waste; Heavy Metals; Sorption Isotherm; Capacity 1. Introduction In this work, A two new hybrid “organic-inorganic” composite ion exchangers (SAM and FAM) were syn- The long-lived radionuclides in radioactive waste have been considered to be dangerous pollutants, and their migration with groundwater is strongly affected by ad- sorption on the geologic materials. The presence of ra- dionuclides and toxic metals in wastes is a major envi- ronmental concern. Such wastes arise from technologies producing nuclear fuels, and from laboratories working with radioactive materials [