Calculation of the Rydberg Energy Levels for Francium Atom英文文献资料.docVIP

HindawiPublishingCorporation PhysicsResearchInternational Volume2010,ArticleID203497,5pages doi:10.1155/2010/203497 ResearchArticle CalculationoftheRydbergEnergyLevelsforFranciumAtom HuangShizhongandSunQiufeng CollegeofPhysicsandElectricalInformation,AnhuiNormalUniversity,Wuhu241000,China CorrespondenceshouldbeaddressedtoHuangShizhong,huangsz@ Received18September2010;Revised9November2010;Accepted11November2010 AcademicEditor:N.Bigelow Copyright?2010H.ShizhongandS.Qiufeng.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttribution License,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperly cited. nd D3/2(n=6–50),andnd 2 2 D5/2(n=6–50)spectrumseriesforfranciumatomarecalculated.Thecalculatedresultsare(inn=excellent8–50), Basedontheweakestboundelectronpotentialmodeltheory,theRydbergenergylevelsandquantumdefectsofns S1/2 2 agreementwiththe74knownexperimentallymeasuredlevels(theabsolutedi?erenceislessthan0.03cm?1)and58energylevels forhighlyexcitedstatesarepredicted. 1.Introduction in francium were calculated by Safronova et al. [11], the calculations were based on the relativistic single-double approximation in which single and double excitations of Dirac-Hartree-Fockwavefunctionsareincludedtoallorders inperturbationtheory.In2004,pseudorelativisticHartree- Fock method including core-polarization e?ects was used to investigate the radiative parameters for electric dipole transitionsintheionsRaII,AcIII,ThIV,andUVIalong thefranciumisoelectronicsequencebyBi′emontetal.[13]. Alsoin2004,relativisticHartree-Fockmethodwithseveral correlations was used to perform ab initio calculation of isotope shifts for isotopes of francium (from A = 207 to A=228)byDzubaetal.[14].In2005,radiativecorrections to E1 matrix elements for ns-np transitions in the alkali- metal atoms lithium through francium are evaluated by SapirsteinandCheng[15].In2006,relativisticthird-order and all-order methods were used to