Soft X-Ray Irradiation Effects of Li2O2, Li2CO3 and Li2O Revealed by Absorption Spectroscopy 英文参考文献.docVIP

SoftX-RayIrradiationEffectsofLi2O2,Li2CO3andLi2O RevealedbyAbsorptionSpectroscopy RuiminQiao1,2,Yi-DeChuang2,ShishenYan1*,WanliYang2* 1SchoolofPhysics,ShandongUniversity,Jinan,Shandong,China,2AdvancedLightSource,LawrenceBerkeleyNationalLaboratory,Berkeley,California,UnitedStatesof America Abstract Li2O2, Li2CO3, and Li2O are three critical compounds in lithium-air and lithium-ion energy storage systems. Extensive measurementshavebeencarriedouttostudythechemicalspeciesandtheirevolutionsatdifferencestagesofthedevice operation.Whilex-rayspectroscopy hasbeendemonstrated tobe one ofthemostpowerful toolsforsuchpurpose,no systematicstudyontheirradiationeffectshavebeenreported.Herewecarryoutextensivetime,position,andirradiation dependentLiK-edgesoftx-rayabsorptionspectroscopyonthesecompoundswithsofarthebestenergyresolution.The ultra-high resolution in the current study allows the features in the absorption spectra to be well-resolved. The spectral lineshape thus serves as the fingerprints of these compounds, enabling the tracking of their evolution under x-ray irradiation.WefoundthatbothLi2O2andLi2CO3evidentlyevolvetowardsLi2Ounderthesoftx-rayirradiationwithLi2CO3 exhibitingasurprisinglyhighersensitivitytox-raysthanLi2O2.Ontheotherhand,Li2Oremainsthemoststablecompound despite experiencing substantial irradiation dose. We thus conclude that high resolution soft x-ray spectroscopy could unambiguously fingerprint different chemical species, but special cautions on irradiation effects would be needed in performingtheexperimentsandinterpretingthedataproperly. Citation:QiaoR,ChuangY-D,YanS,YangW(2012)SoftX-RayIrradiationEffectsofLi2O2,Li2CO3andLi2ORevealedbyAbsorptionSpectroscopy.PLoSONE7(11): e49182.doi:10.1371/journal.pone.0049182 Editor:RuihuaHe,BostonCollege,UnitedStatesofAmerica ReceivedSeptember24,2012;AcceptedOctober8,2012;PublishedNovember7,2012 Copyright: ? 2012 Qiao etal. This is an open-access article distributed under the terms of the Creative Commons Attribution