Vapochromic Behaviour of M[Au(CN)2]2-Based Coordination Polymers (M = Co, Ni) 英文参考文献.docVIP

Sensors 2012, 12, 3669-3692; doi:10.3390/s120303669 OPEN ACCESS sensors ISSN 1424-8220 /journal/sensors Article Vapochromic Behaviour of M[Au(CN)2]2-Based Coordination Polymers (M = Co, Ni) Julie Lefebvre, Jasmine L. Kor?ok, Michael J. Katz and Daniel B. Leznoff * Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC V5A 1S6, Canada; E-Mails: jlefebvr@ucalgary.ca (J.L.); jkorcok@tru.ca (J.L.K.); mjkatz@sfu.ca (M.J.K.) * Author to whom correspondence should be addressed; E-Mail: dleznoff@sfu.ca; Tel.: +1-778-782-4887; Fax: +1-778-782-3765. Received: 10 February 2012; in revised form: 9 March 2012 / Accepted: 13 March 2012 / Published: 16 March 2012 Abstract: A series of M[Au(CN)2]2(analyte)x coordination polymers (M = Co, Ni; analyte = dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), pyridine; x = 2 or 4) was prepared and characterized. Addition of analyte vapours to solid M(μ-OH2)[Au(CN)2]2 yielded visible vapochromic responses for M = Co but not M = Ni; the IR νCN spectral region changed in every case. A single crystal structure of Zn[Au(CN)2]2(DMSO)2 revealed a corrugated 2-D layer structure with cis-DMSO units. Reacting a Ni(II) salt and K[Au(CN)2] in DMSO yielded the isostructural Ni[Au(CN)2]2(DMSO)2 product. Co[Au(CN)2]2(DMSO)2 and M[Au(CN)2]2(DMF)2 (M = Co, Ni) complexes have flat 2-D square-grid layer structures with trans-bound DMSO or DMF units; they are formed via vapour absorption by solid M(μ-OH2)[Au(CN)2]2 and from DMSO or DMF solution synthesis. Co[Au(CN)2]2(pyridine)4 is generated via vapour absorption by Co(μ-OH2)[Au(CN)2]2; the analogous Ni complex is synthesized by immersion of Ni(μ-OH2)[Au(CN)2]2 in 4% aqueous pyridine. Similar immersion of Co(μ-OH2)[Au(CN)2]2 yielded Co[Au(CN)2]2(pyridine)2, which has a flat 2-D square-grid structure with trans-pyridine units. Absorption of pyridine vapour by solid Ni(μ-OH2)[Au(CN)2]2 was incomplete, generating a m