钛酸铋钠钾压电薄膜的制备及弛豫性能表征.pdfVIP

Abstract Relaxor ferroelectrics belong to a special class of disordered materials that, because of their extraordinary piezoelectric and dielectric properties, show enormous potential for industrial applications such as next-generation sensors, actuators and transducers that convert between mechanical and electrical forms of energy. However, relaxor ferroelectrics with excellent properties, such as PLZT, PMN-PZT, PZN-PZT, have been widely used in MEMS device, which are detrimental to environment and human health duiring preparation and application for they include huge amount of lead oxide (senventy percent of total raw material). Great interest on lead-free composition with the relaxor behavior for lead-free ferroelectrics has been aroused in recent years because of the environmentally friendly applications, such as dielectrics for capacitors, actuators, etc. Because bismuth sodium titanate Na0.5Bi0.5TiO3 (NBT) exhibits strong ferroelectricity at room temperature and high Curie temperature, it is regared as one of lead-free piezoelectric materials. Pure NBT suffers from its high conductivity and large coercive field. Therefore it is difficult to obtain the desired piezoelectric properties. In comparison with pure NBT, NBT-based solid solutions modified with BaTiO3 and K0.5Bi0.5TiO3 (KBT) show the improved piezoelectric and dielectric properties due to the existence of MPB. The material research from bulk to film is largely driven by miniaturization of electronic devices, the new micro-electromechanical systems (MEMS) and achievement of breakthrough on