铌酸钾钠基无铅压电陶瓷的常压烧结致密化.pdfVIP

ABSTRACT Today, the researches of the lead-free piezoelectric ceramics and their applications are extremely important as a result of the implementing of the strategy in which the society of the world can sustainably develop, and the strengthening of the consciousness of environmental protection. (Na K )NbO (NKN) system ceramics exhibit typical ABO -type 0.5 0.5 3 3 perovskite structure. The Nb, K and Na metals are environment-friendly and human-friendly materials. Its performance is much better than other lead-free piezoelectric ceramic system, such as high piezoelectricity and high Curie temperature. Therefore, NKN ceramics has been paid to a lot attention and become the main promising candidate for the lead-containing piezoelectric materials. In this thesis, lead free piezoelectric ceramic of (Na1/2K1/2)NbO3 (NKN) and 0.95NKN-0.05AB (AB=CaTiO3 (CT), LiSbO3 (LS), LiTaO3 (LT), (Ba1/2Sr1/2)TiO3 (BST)) system were prepared by the conventional solid-state reaction method sintered at air pressure. The influences of the second component and the sintering conditions on the phase structure, the density and electric properties of the NKN-based ceramics were studied systematically. X-ray diffraction (XRD) measurement confirms that phase-pure perovskite NKN ceramics of all the composition can be prepared by the conventional solid-state reaction method via atmosphere sintering at certain sintering temperature range. Based on the integral analysis of the microstructure, relative density