La-BiVO4催化剂的制备及其光催化还原CO2.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 478 CHEMICAL ENGINEERING OF OIL GAS 2013 La—BiVO4催化剂的制备及其光催化还原CO2 王剑波 徐燕峰 孙 媛 (1．安徽理工大学化学工程学院 2．健雄职业技术学院生物与化学工程系) 摘 要 采用化学沉淀法制备了La—BiVO 光催化剂，并应用于光催化还原CO ／H O体系 中。通过TG—DTA、DRS、XRD对光催化剂进行表征，研究了焙烧温度等对光催化性能的影响。结 果表明，800 C煅烧制得的单斜相 La—BiVO 活性最高。在催化剂用量 0．8 g／L、反应时间8 h、 CO2流量250 mL／min、反应温度7O℃、反应液中NaOH和Na2SO。的浓度均为0．10 mol／L的条 件下，甲醇产率高达290．18／~mol／g。 关键词 La—BiVO 光催化 二氧化碳还原 甲醇 中图分类号：TE642 文献标志码：A DOI：10．3969／j．issn．1007—3426．2013．05．008 Preparation of La。BiVO4 catalyst and its photocatalytic reduction property of CO2 Wang Jianbo ，Xu Yanfeng ，Sun Yuan。 (1．Department of Chemical Engineering，Anhui University of Science and Technology． Huainan 232001，Anhui，China；2．Department of Biological and Chemical Engineering． Chien shiung Institute of Technology，Suzhou 215400，Jiangsu，China) Abstract：ZLa—BiV04 photocatalyst was prepared by chemical precipitation method，and its photocatalytic reduction of CO2 in water was examined．The catalyst was characterized bv TG— DTA，DRS and XRD technology，and the effect of roasting temperature and other conditions on the activity of photocatalytic reduction of CO2 were studied The results showed that monoclinic ． phase La—BiVO4 calcined at 800。C has the highest activity．W hen the amount of catalyst was 0