木质纤维素气凝胶在离子液体中的制备及表征.pdfVIP

科技导报2014。32(4／5) 1^n^n^f．kjdb．org 针垒…。 木质纤维素气凝胶在离子液体中的 制备及表征 卢芸’，邱坚2，孙庆丰’，李坚’ 1．东北林业大学材料科学与工程学院，哈尔滨150040 2．西南林业大学材料工程学院，云南省木材胶黏剂及胶合制品重点实验室，昆明650224 摘要为制备一种新型的木质基新材料，采用离子液体将木粉溶解，经循环冻融工艺处理结合临界点干燥即得木质纤维素气凝 表征。结果表明。制备出的木质纤维素气凝胶具有的三维纤丝网状结构。通过冻融循环可以逐渐增强为片状结构。纳米纤丝的网 络支架影响了气凝胶的多层级微米一纳米形貌；木质纤维素气凝胶的结晶度随冻融次数的增加呈先增加后减小的变化趋势；并阐 释分析了木质纤维素气凝胶的形成机理。 关t词木质纤维素气凝胶；离子液体；三维网络结构 中圈分类号TQ050．4+25 文l-I标志码A doi10．3981／j．issn．1000—7857．2014．h1．003 andCharacterizationof Preparation LignocelluloseAerogel ● T ● T● ●1 ln10nlC LlqUln LU Jian2，SUN Jian Yunl，QIU Qingfen91，LI 1．MaterialScienceand 150040，China EngineeringCollege，NortheastForestryUniversity，Harbin 2．Yunnan ofWoodAdhesivesandGlue ofMaterials Engineering，SouthwestForestry KeyLaboratory Products，College 650224，China University，Kunming Ab皱随ctTo anovelwood—based without wasdissolvedinionic a material．wood prepare powder anypre—treatment liquid．With circulated andcritical Was procedure dryingmethod，lignocelluloseaerogel freezing-thawing point successfully featuresand characteristicsofthe materialwerecharacterizedfieldemissionelectron crystalline as—prepared by microscopy(SEM)， transmissionelectron resultsshowedthatthe microscope，andX—raydiffraction(XRD)．The preparedlignocelluloseaerogelpossesses a structureof fibrillarnetworkandothernovelnanostructurccellulose three—dimensional material