柠檬酸凝胶燃烧法制备GGG∶Eu3+,Bi3+多晶发光粉体及其表征.pdfVIP

第35卷第3期 硅 酸 盐 通 报 v。1．35N。．3 Bi3+ 柠檬酸凝胶燃烧法制备GGG：Eu3+ 多晶发光粉体及其表征 刘慧敏 ，孙晶，张 敏，潘柳，张鑫洋，于文生 (长春理工大学化学与环境工程学院，长春130022) GGG相。SEM显示样品晶粒呈球形或类球形，直径约60am。PL分析显示样品最强发射峰位于592nm处，属于 Eu“的5Do一7‘磁偶极跃迁。掺杂Bi3+的样品发光强度明显高于未掺杂Bi3+的样品，而发射峰位置不变，当掺杂的 摩尔分数达到菇=5％时，GGG：E蠢．乞，si3,+的发光强度达到最大值。再之后随Bi¨掺杂浓度的增加发光强度减 弱，这可能是因为Bi3+和Eu“之间的能量传递方式主要是偶极．偶极作用，传递效率主要决定于两种离子间距离。 关键词：GGG：Eu”，Bi“；凝胶燃烧法；多晶发光粉体 中图分类号：TFl2 文献标识码：A andCharacterizationof Preparation LuminousPowdersCitricAcid CombustionMethod by Sol-gel LIU Hui-min，SUNJing，ZHANG施n，PANLiu，ZHANG Xin-弘昭，YUWen—Sheng ofChemicalandEnvironmental ofScienceand (School Engineering，ChangchunUniversity Technology，Changchun130022，China) Abstract：The luminous were thesizedasol- GGG：Eu3+．Bi3+polycrystallinepowderssuccessfullysyn by combustionwith andcitricaCid．The gel strategyGd203，Ga203，Eu203，Bi(N03)3·5H20 prepared materialswerecharacterized electron byX—raydiffraction(XRD)，Scanningmicroscope(SEM)，Fourier transfo珊infrared(Fr—IR)，and XRDandFT—IRresuhsshowedthatthe photoluminescence(PL)．The structureofthe wasGGG theSEM showedthatthe were powders phase．And image powdersnearly or withthediameterabout60am．TheresultsofPLshowedthatthemaximum sphericalgrains spherical emission fluorescence was592 Was tothe of nm，which peak