无机柱撑膨润土对有机锡废水COD的吸附研究.pdfVIP

● 工业给排水 ● 无机柱撑膨润土对有机锡废水COD的吸附研究 孙长顺 金奇庭 郭新超 秦莉红 张 渫 (西安建筑科技大学环境与市政工程学院，西安 710055) 摘要 利用原土、羟基铁膨润土和羟基铁铝柱撑膨润土，进行了吸附有机锡废水中CODcr的试 验。研究了膨润土投加量、吸附pH、时间和等温线的变化规律。结果表明，达到吸附平衡的时间为 2 h；随着吸附pH由小到大的变化，CODc 的吸附去除率在一定范围内波动；膨润土的投加量宜大于 4 g／L；吸附符合Henry等温式；膨润土的层间距、吸附位的数量及活性是决定对吸附性能的关键因 素；吸附容量的大小和吸附作用的强弱顺序为：羟基铁铝膨润土羟基铁膨润土原土。 关键词 膨润土 柱撑 有机锡 等温线 Study on adsorption of COD in organotin wastewater by pillared montmorillonites Sun Changshun，Jin Qiting，Guo Xinchao，Qin Lihong，Zhang Die (School of Environmental and Municipal Engineering．Xi’an University of Architecture Technology。X ’an 710055。China) Abstract：The adsorption of CODcr in organotin wastewater by hydroxyl—Fe，hydroxyl—Fe—A1 pillared montmorillonites and the raw montmorillonite was presented in this paper．The factors Of sorbent dosage，pH，reaction time and isotherm in adsorption process were studied respectively． The results showed that the adsorption balance could be achieved in 2 hours．The adsorption ratio fluctuated in special ranges with the variety of pH value．The dosage of montmorillonite should be more than 4 g／L．The adsorption isotherm of CODcr was agreed with Henry equation．The inter— layer space of montmorillonite beds and quantities of adsorption site played an important role in ad— sorption process．In adsorption of CODcr in the organotin wastewater，the sequence of the amount adsorbed and adsorption affinity is that：hydroxyl—Fe—A1 hydroxyl—Feraw montmorillonite． Keywords：Montmorillonite；Pillared~Organotin；Isotherm 膨润土是一种以蒙脱石为主要成分的粘土矿 的吸附规律这两个方面。柱撑剂选用的金属离子分 物，具有较大的比表面积和较强的吸附能力，已被广 别有铝、铁、钛、锆、锰等，其中以具较大体积和较高 泛应用于环境保护、化工、医药、食品等行业。为了 电荷的羟基铝离子(Keggin)为最，而对羟基铁离子 进一步提高吸附性能，可以采用不同方式对膨润土 的研究较少_1]。柱撑膨润土吸附的污染物质分为无 进行改性，无机柱撑是其中主要的一种。柱撑膨润