催化动力学电位法测定海产品中微量碘.pdfVIP

安徽农业科学，Journal of Anhui Agri. Sci. 2011 ,39(24) : 15010 -15012 曾任编. -4-商责任枝对李去 催化动力学电位法测定海产品中微量破 赵永福1 ，晋晓苹2 (1· 贺州学院化学与生物工程系，广西贺州 54组∞;2. 河南化工职业学院，河南郑州 45∞42) 摘要 [目的]建立一种测定海产品中微量模的催化动力学电位法。[方法]采用单因素试验考察了催化动力学电位法测定海产品中微 量棋的影响因素，并测定了海带( l.amiooria japo即a) 、紫菜(Porphyra 16.阳αKjellman) 和海虾中模的含量。[结果]建立的催化动力学电 位法测定琪含量的线性范围为 8 -28 nglml ，方法的检出限为 5.2 略/时，回收率大于97.0% ，相对标准偏差(RSD) 小于l.lì岛，方法准确 可靠。采用该法测定的海带、紫菜和海虾中峡的含量分别为 3 1. 98 、27.38 、 18.40μ在旬， RSD 分别为1.481岛、0.70% 、1. 61 % 0 [结论]该研 究建立的方法不需要进光，操作简单，温度控制方便，用于海产品中微量模的测定结果令人满意。 关键词 催化动力学电位法;甲基紫离子选择性电极;瑛;海产品 中图分类号 537 文献标识码 A 文章编号 。当17 -6611 (2011)24 -15010 -03 Determination of Micro Amounts of Iodide in S幅food based on Catalytic Kinetic Potentiom由ic Me伽od ZHAO Yong- fu et al (Department of Chemis町 and Biology E咿neering ， He巾u University , Hezhou , Guangxi 5428∞) Abstract [ Objective] 四e aim w阻 to establish a catal严ic kinetic potentiometric method of determining the content of micro amounts of io- dide in seafood. [Method] The influencing factors were observed when the catalytic kinetic potentiometric method w国 used ωdetermine the content of iodide in seafood , and used it to determine the content of iodide in L japonicα ， P. tenera Kjellman and 盹a shrimps. [R回ult] The linear range of established catalytic kinetic potentiometric method w嗣 8 - 28 nglml when determining 由e content iodide , the detection limit was 5. 2 nglml , the recoveηrate w嗣 more 由an 97. 0% , and relative standard deviation ( R5D) w国 more 由.an 1. 1% ，四 this method w国 ac­ curacy and reliable. 四e content of iodide in L japonica , P. te时ra Kjellman and sea shrimps determined by established catalytic kinetic 伊 tentiometric method w皿3 1. 98 , 27. 38 , 18. 40 j.Lg/ g respectively and RSD w嗣1. 48% , 0.70% , 1. 61 % respectively. [Conclusion] The de- termination method has no necess缸Y to ke