化学镀镍-磷合金镀层中磷的测定.pdfVIP

.39. 2012 年 1 月 电镀与精饰 第34 卷第 l 期(总 226 期) 文章编号:1001-3849(2012)01-0039-03 化学镀镇-磷合金镀层中磷的测定 刘定富，崔东，魏世洋 (贵州大学化学与化工学院，贵州贵阳 550003) 摘要:准确、简便地测定媒-磷合金镀层的磷对化学镀绿工艺具有重要作用。采用浓硝酸退镀锥·磷合 金镀层→高锺酸押氧化→亚硝酸纳还原→加水定容的方法制备实验溶液，然后分别用磷锢辄黄分光 光度法、磷细酸接容量法分析试液中的磷，再换算出镀层中磷的质量分数，并与标准方法测定结果对比。 结果表明:光度法测定的相对误差为7.939毛，相对标准偏差为 4.389毛;容量法测定的相对误差为-1.83% , 相对标准偏差为 0.829毛。容量法具有准确、简便的优点，可在生产实际和实验研究中推广应用。 关键词:化学镀媒·磷合金;磷;磷钮辄黄光度法;磷细酸接容量法 中图分类号: TQ153.2 文献标识码:B Determination of Phosphorus Content in Electroless Ni -P Alloy Coating LIU Ding-fu , CUI Dong ,WEI Shi-yang (Chemistry and Chemical Engineering Institute , Guizhou University , Guiyang 550003 , China) Abstract: The test solution was prepared by Ni-P coating stripping with concentrated nitric acid , oxidi- zing with pot臼sium permanganate , reducing with sodium nitrite and watering to constant volume. Phos- phorus concentration in the solution was determined by phosphorus molybdenum vanadium yellow spectro- photometry and ammonium phosphomolybdate volumetric method , and then converted to phosphorus con- tent in the Ni-P coating and compared with 由at by standard method. Results showed that the relative er- ror of spectrophotometry determination was 7.939岛， the relative standard deviation of that was 4. 38% while the relative error of volumetric method was - 1. 83% , the relative standard deviation of that was 0.82%. The volumetric method could be used in experimental research as well as in the field of produc- tion practices because of its simplic