城市污泥两段式催化热解制合成气研究 - 中国水网.pdf

中国环境科学 2015,35(3) ：804~810 China Environmental Science 城市污泥两段式催化热解制合成气研究 1,2 1 2 1 2* 常风民 ,王启宝 ,SEGUN Giwa ,贾晋炜 ,王凯军 (1. 中国矿业大学(北京)化学与环境工程学院,北京 100083；2.清华大学环境学院,环境模拟与污染控制国家重点联合实验室,北京 100084) 摘要：为了把城市污泥中温热解产生的挥发性产物转化为可直接利用的洁净可燃性气体或重要的化工原料合成气,采用两段式热解装置对 城市污泥进行了催化热解实验研究,讨论了不同催化剂对城市污泥热解挥发性产物的催化裂解能力,结果表明:城市污泥在热解终温 500℃, 热解液产率最大,超过 500℃,热解液产率减少,热解气增多,固相产率基本不变;城市污泥热解液的裂解温度需在 900℃以上,产生的气体组分 主要为 H 、CO、CH 等小分子非冷凝性气体;Ni/分子筛复合催化剂对热解液转化为合成气的作用效果较好,合成气体(H +CO)体积含量占 2 4 2 气体总量的 85%以上. 关键词：城市污泥；两段式催化热解；合成气；Ni/分子筛 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2015)03-0804-07 1,2 1 Two-stage catalytic pyrolysis of sewage sludge for syngas production. CHANG Feng-min , WANG Qi-bao , SEGUN 2 1 2* Giwa , JIA Jin-wei , WANG Kai-jun (1.Department of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China ；2.State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China). China Environmental Science, 2015,35(3) ：804~810 Abstract ：Syngas production from sewage sludge via a two-stage catalytic pyrolysis reactor was investigated, for further utilization of volatile products evolved during one-stage pyrolysis. In addition, the catalytic performance of different catalysts was studied. The results showed that the maximum liquid (aqueous and oil phase) yield was obtained at a final pyrolysis temperature of 500 ℃. Moreover, when the pyrolysis temperature was above 500℃, increasing gas yield and relative stable solid yield were observed. The furt