聚（丙烯酰胺-丙烯酸十八醇酯）疏水缔合行为及环境影响因素.pdfVIP

第28卷第6期 青 岛科技 大学 学 报(自然科学版) Vo1．28 No．6 2007年 1 2月 Journal of Qingdao University of Scienceand Technology(Natural Science Edition) Dec．2007 文章编号：1672—6987(2007)06—0525—04 聚(丙烯酰胺一丙烯酸十八醇酯) 疏水缔合行为及环境影响因素 于 晖，冯 莺 ，赵季若，李俊源，邢 政 (青岛科技大学 橡塑材料与工程教育部重点实验室，山东青岛266042) 摘 要：研究了疏水单元丙烯酸十八醇酯与丙烯酰胺一丙烯酸十八醇酯共聚物水溶液性 质的关系，及乳化剂SDS、NaC1等因素对共聚物疏水缔合行为的影响。结果表明，疏水单 元丙烯酸十八醇酯在共聚物水溶液中的摩尔分数0．64 左右时，共聚物水溶液表现出高 的表观黏度；一定质量分数(O．5％)SDS与共聚物水溶液可以形成特殊的微结构，有极强 的协同效应，共聚物水溶液的表观黏度迅速增大，其值从未加SDS的35 mPa·S增加到 6000 mPa·S；当共聚物水溶液处于临界缔合浓度以上时，NaC1的加入使表观黏度迅速上 升，共聚物表现出较好的抗盐性。 关键词：疏水缔合；丙烯酸十八醇酯；表观黏度 中图分类号：O 631．3 文献标识码：A Hydr0ph0bically Associating of Acrylamide—octadecyl Acrylate Copolymer and Influencing Factors YU Hui，FENG Ying，ZHAo ji—ruo，LI Jun—yuan，XING Zheng (Key Laboratory of Rubber plastics，Ministry of Education， Qingdao University of Science and Technology，Qingdao 266042，China) Abstract：A series of hydrophobically associating copolymers of acrylamide with octade— cyl acrylate were synthesized in this paper．The effects of amount of OA in the copoly— mers，SDS concentration，and NaC1 concentration on the rheological behavior of copoly— mers aqueous solution were investigated．The results showed that the copolymer aque— OUS solution have a higher value of apparent viscosity，when the amount of OA in copol— ymers was about 0．64 ．The apparent viscosity of copolymer aqueous solution in- creased greatly with the 0．5 9／6 concentration of SDS，ranging from 35 mPa·S up to 6000 mPa·S．The addition of NaC1 to the polymer solution led to a rapid rise of the ap— parent viscosity of the solution，contrary to what is observed in partially hydrolyze poly