グラフェンの选择的化学修饰による次世代半导体の创出.pdf

Annual Report No.28 2014 グラフェンの選択的化学修飾による次世代半導体の創出 Creation of Novel Graphene Semi-Conductors by Selective Chemical Functionalization H2551 代表研究者 田　原　一　邦 大阪大学　基礎工学研究科　助教 Kazukuni Tahara Assistant Professor, Graduate School of Engineering Science, Osaka University Development of new methodologies to functionalize graphenes at the nanometer scale is subject of keen interest for scientists in different research fields because of perspective of various applications. Among various methodologies, supramolecular assembly provides an attractive approach to form nanopatterns on graphenes, since many organic molecules is known to form well-defined patterns on graphitic surfaces via physisorption. Here we show that formations of two-dimensional (2D) porous molecular networks on single or multi-layered graphenes fabricated on different substrates by self-assembly of dehydrobenzo[12]annulene (DBA) derivatives having six alkoxy chains at the interfaces between organic liquid and graphenes. Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) investigations revealed that honeycomb networks formed by DBA derivatives are highly flexible and they follow the topological features of the graphene surfaces without any discontinuity, irrespective of the step-edges present in the substrate underneath. The investigation on the stability of these networks confirmed the robustness under ambient air conditions. The robust yet flexible DBA network formed on graphene surface is a useful platform for further modification of graphene surface by co-adsorption of other molecular species at the pore and the production of novel sensor which can recognize targeted molecule. 研究目的