碳热还原法制取碳氮化钛的热力学原理分析 - 昆明理工大学学报.pdf

31 5 ( ) ol. 31 No. 5 2006 10 Journal ofKunm ingUniversity of Science andTechnology ( Science andTechnology) Oc.t 2006 1, 2 2 1 1 方民宪 , 彭金辉, 陈厚生, 陈德明 ( 1. , 617000; 2. , 650093) : 分析碳热还原法制取T i(C, N)的热力学原理, 结果表明, 合成过程伴随着相变, 当T iO 颗 2 粒和 C颗粒均 混合时, 还原反应主要依赖于 CO /CO 传质的气固反应, 当 T iO 颗粒表面被 C 2 2 包膜时,主要是碳和钛氧化物之间的固固反应.升高温度有利于还原进行,钛氧化物的开始还原 温度随气相中的 CO分压降低而降低,但T i( C, N) 中的C, N含量则取决于温度和N 压力. 2 : 碳氮化钛; 碳热还原; 热力学 : TF803. 13 : A : 1007- 855X( 2006)05- 0006- 08 A Thermodynamics- BasedAnalysisofMaking Titanium CarbonitrideThrough Carbon ThermalReduction 1, 2 2 1 1 FA NG M in-x ai n , PENG J in-hu i, CHEN Hou-sheng , CHEN De-m ing ( 1. Panzhihua Iron and Steel Institute, Panzhihua, Sichuan 671000, China; 2. Faculty ofM aterials andM etallurgicalEngineering, Kunm ing University ofScience andTechnology, Kunm ing 650093, China) Abstract: Thermodynam ic principle of making T i( C, N ) by carbon- heat reducing is analyzed. The result shows that synthesizingprocess is accompanied by phase change. WhenT iO and carbon grain arem ixed, the re- 2 ductive reactionmainly depends on CO /CO gas- solid transm itted reaction. W hen the surface ofT iO particle is 2