原创力文档the effect of annealing treatments on spherulitic morphology and physical ageing on glass transition of poly lactic acid (plla)退火处理的效果在球状的形态和物理老化对聚乳酸(丙交脂)玻璃化转变.pdfVIP
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the effect of annealing treatments on spherulitic morphology and physical ageing on glass transition of poly lactic acid (plla)退火处理的效果在球状的形态和物理老化对聚乳酸(丙交脂)玻璃化转变
Materials Sciences and Applications, 2011, 2, 439-443 439
doi:10.4236/msa.2011.25058 Published Online May 2011 (http://www.SciRP.org/journal/msa)
The Effect of Annealing Treatments on Spherulitic
Morphology and Physical Ageing on Glass
Transition of Poly Lactic Acid (PLLA)
El-Hadi Ahmed Mohamed1,2
1Department of physics, Faculty of Applied Science, Umm al-Qura University, Mecca, Kingdom of Saudi Arabia; 2Department of
Basic Science, Higher Institute for Engineering and Technology, El Arisch, Nord Sinai, Egypt.
Email: Bioplastics.elhadi1962@
Received October 29th, 2010; revised December 24th, 2010; accepted May 9th, 2011.
ABSTRACT
Spherulitic morphology of pure poly lactic acid (PLLA) PLLA have investigated after thermal annealing. The morphol-
ogy of spherulite of pure poly lactic acid (PLLA) PLLA have investigated after thermal annealing. The effect of both
annealing temperature and crystallization temperature on the formation of cracks was described by polarized optical
microscope (POM). Non banded spherulite (fibrils ) with cracks was detected in PLLA film after annealing at 160˚C
(180 min.) and isothermal crystallization temperatures at 140˚C and 150˚C. With increasing temperature after anneal-
ing treatment the size of spherulite is increased and more cracks are formed. The maximum growth rate of spherulites
was found at 130˚C. The physical ageing was carried out by annealing the PLLA sample at room temperature for sev-
eral annealing time (ta) from 0 h to 720 h. The enthalpy relaxation has been studied by differential scanning calorimetry
(DSC) through analysis of the endothermic peak of glass transition temperature, which increased and shifted towards
higher temperature as the annealing time increased.
Keywords : Poly Lactic Acid (PLLA), Morphology, Non-Banded Spherulites, Annealing, Polarized Optical Microscopy,
Physical Ageing
1. Introd
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