simple ion transfer at liquidliquid interfaces在liquidliquid简单离子传输接口.pdfVIP

Hindawi Publishing Corporation International Journal of Electrochemistry Volume 2012, Article ID 462197, 34 pages doi:10.1155/2012/462197 Review Article Simple Ion Transfer at Liquid |Liquid Interfaces ´ L. J. Sanchez Vallejo, J. M. Ovejero, R. A. Fernandez, and S. A. Dassie Instituto de Investigaciones en Fisicoquımica de Cordoba (INFIQC), CONICET y Departamento de Fisicoquımica, ´ ´ ´ Facultad de Ciencias Quımicas, Universidad Nacional de Cordoba, Ciudad Universitaria, Cordoba X5000HUA, Argentina ´ ´ ´ Correspondence should be addressed to S. A. Dassie, sdassie@.ar Received 17 February 2012; Accepted 14 March 2012 Academic Editor: Shen-Ming Chen Copyright © 2012 L. J. Sanchez Vallejo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The main aspects related to the charge transfer reactions occurring at the interface between two immiscible electrolyte solutions (ITIES) are described. The particular topics to be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimental methodologies. Concerning the theoretical procedures, different computational simu- lations related to simple ion transfer are reviewed. The main conclusions drawn from the most accepted models are described and analyzed in regard to their relevance for explaining different aspects of ion transf