第四章 电化学基础（The fourth chapter is electrochemical basis）.docVIP

第四章 电化学基础（The fourth chapter is electrochemical basis） The fourth chapter is electrochemical basis Section 1 primary cell 1, the concept of chemical energy into electrical energy device called primary battery _______ 2. Composition conditions: two electrodes with different activity, electrolyte solution, electrodes connected by wire and inserted into electrolyte to form closed loop 3 、 electronic flow direction: external circuit: negative electrode - lead wire - positive electrode In the circuit: move to the salt bridge anion in electrolyte solution of the negative electrode in electrolyte solution to cationic saltbridge cathode. 4 electrode reaction: a case study of zinc copper galvanic cell: Negative: oxidation: Zn2e = Zn2 + (active metal) Cathode reduction reaction:: = H2 = 2H2e (less active metal) The total reaction type: Zn+2H+=Zn2++H2 = 5, positive and negative judgments: (1) from the electrode material: generally more active metal as negative electrode; or metal as negative electrode, non metal as positive electrode. (2) from the direction of the electron flow, the negative electrode flows into the positive electrode (3) the anode flows from the current direction to the negative electrode (4) the cation flows to the positive electrode according to the direction of the ion movement in the electrolyte solution, and the anion flows to the negative electrode (5) according to the experimental phenomena of __ dissolved a negative __ II weight or have a positive bubble Second chemical batteries 1. Classification of batteries: chemical batteries, solar cells, atomic energy batteries 2. Chemical battery: a device that converts electricity directly into electrical energy by chemical energy 3. Classification of chemical batteries: primary batteries, two batteries, fuel cells I. primary batteries: common primary batteries: alkaline zinc manganese batteries, zinc silver batteries, lithium batteries, etc. Two and two batteries 1 and two batteries: after discharge can be re