木纤维还原电解锰阳极泥制备硫酸锰工艺研究赵世珍韩凤兰滕于江王.docVIP

木纤维还原电解锰阳极泥制备硫酸锰工艺研究 赵世珍 韩凤兰 滕於江 王德吉 柴永恒 李雪岩 哈甫热 （北方民族大学材料科学与工程学院 银川 750021） 摘要： 采用木纤维为还原剂湿法还原浸出阳极泥中的锰，硫酸为浸出剂来制备硫酸锰。通过正交试验及单因素变量实验，考察了木屑用量、浓硫酸用量、熟化时间、熟化温度、福镁钠用量对锰浸出率及回收率的影响。用硫酸亚铁铵滴定法(GB/T 1506-2002)和电感耦合高频等离子体ICP化学分析方法，探索出最优的工艺条件：木纤维用量为20%，液固比为6:1时，浓硫酸加入量为9.6%，熟化时间为80min，熟化温度为425℃，福镁钠用量为8%，锰回收率为93.12%，锰的浸出率为99.18%，在最优条件下铅、砷的除去率都在99.7%以上。 中图分类号：TQ137.12 文献标识码：A 文章编号 关键词：锰阳极泥；硫酸锰；浸出率；回收率；重金属 Study on Preparation of manganese sulfate by reduction of wood fiber with electrolytic manganese anode slime Shizhen Zhao, Fenglan Han *,Yujiang Teng,Deji Wang,Yongheng Chai,Xueyuan Li,Fure Ha Beifang University of Nationalities, Yinchuan, 750021 Abstract: Xylon was used as reductant to reduction leaching manganese anode sludge, sulfuric acid was used as leaching agent to prepare manganese sulfate. The effects of the amount of wood chips ,the amount of concentrated sulfuric acid, curing time,curing temperature,the amount of sodium magnesium blessing of manganese leaching rate and recovery were investigated by orthogonal experiment and one factor experimental and experiment with simultaneous. Through ferrous ammonium sulphate titration method(GB/T 1506-2002) and iductive coupling high frequency plasma chemical analysis method, the optimal process condition was gained. The amount of sawdust was 20%, liquid to solid ratio was 6:1, the amount of concentrated sulfuric acid was 9.6%, maturing time was 80min, the curing temperature was 425℃, and the dosage of sodium magnesium blessing was 8%.Under this optimal condition, the recovery rate of manganese was 93.12%, and its leaching rate was 99.18%, the removal rates of arsenic and plumbum were both above 99.7%. Keywords: Manganese anode sludge; Manganese sulphate; extraction ratio; recovery ratio; Heavy metal 随着我国钢铁和有色金属工业的迅速发展，对作为钢铁及有色金属工业的添加剂、脱氧剂和脱硫剂的锰及其合金的需求不断增长。与之相应，电解金属锰行业亦得到迅速发展[1?2]，目前我国已成为全球最大的电解锰生产、出口和消费国[3]。 锰阳极泥是在电解金属锰生产中，在阳极产生出的一种黑褐色的副产物，产生的原因主要是在电解金属锰时，电解液中少量的二价锰离子在阳极放电，生成二氧化锰后累计在阳极板上的产物，其锰含量达到41%以上，其主要的成分为四价锰的水合氧化物，并且