水热法制备一维TiO2纳米材料的研究与表征.pdfVIP

水热法制备一维Ti02纳米材料的研究与表征 李振华。 刘中清 王宜超 燕青芝 葛昌纯o (北京科技大学特种陶瓷粉末冶金研究室，北京100083) 摘要：以纳米TiO：粉体和NaOH为原料，采用水热合成法制备了一维TiO：纳米 理的产物后处理进行了表征。结果表明，160℃反应24h后所得产物为无定形TiO。 纳米管，纳米管的外径约10nm，最高比表面积达到533．385m2／g；较高温度的煅 烧处理能够提高产物的晶化程度；纳米管粉体光催化降解亚甲基蓝的能力远优于市 售的P25纳米粉体。 关键词：水热合成法；纳米管；TiO。；光降解 andCharacterizationofoneDimensionalTitaniaNanotubes Investigation from Treament Preparation Hydrothermal LiZhenhua0Liu YichaoYan Ge Zhongqing QingzhiChangchune Wang of CeramicsandPowder (LaboratorySpecial Metallurgy，University ofScienceand 100083) TechnologyBeijing，Beijing have Abstract：We onedimensionaltitaniananotubes prepared byhydrothermal treatment oftitania in NaOHsolution．The ti— nanoparticles aqueous as—prepared taniananotubesand nanotubestreatedatdifferent werecharacterized temperatures a ofmethods byrange includingpowderX—raydiffraction(XRD)，N2adsorption— isotherm desorptionmeasurements(BET)，UV-vis sionelectron SOon．Theseresults thatthe microscopy(TEM)andsuggest as—pre- nanotubesare outerdiametersof sur— pared amorphous，with about．10nm．The faceareaofthenanotubes is aggregatesabout．533．385m2／g．Thecrystallization ofthenanotubesincreasewiththeincreaseoftemperature．Thepreparedphotoca