精美动画超高分子量聚乙烯纤维表面紫外接枝.pptVIP

* * * 小木虫：lizhi258 SHANGHAI RESERCH INSTITUTE OF CHEMICAL INDUSTRY Jun.17th.2010 超高分子量聚乙烯（UHMWPE）纤维表面紫外接枝聚合改性 Surface modification of ultra high molecule weight polyethylene (UHMWPE) fibers via UV radiation grafting polymerization 优异的力学性能,初始模量为100 GPa以上，拉伸强 度大于3．0 GPa 耐低温、耐腐蚀、耐紫外、 射线 低介电系数 ,X波段至mm波段具有优良的介电性能 密度低、高比强度和高比模量，比强度是碳纤维 的3倍，比模量仅次于特级碳纤维 UHMWPE纤维优异性能 ---------------------------------------------------------------------------------------------------------------------------------------- Neema S,Salehi-Khojin A,Zhamu A,et a1.Wettability of nano-epoxies to UHMWPE fibers [J]． Colloid and Interface Science．2006，299：332～341 1.Ultra high molecular weight polyethylene fibers 断裂伸长低、断裂功大，具有很强的吸收能量的 能力，因而具有突出的抗冲击性和抗切割性 1.Ultra high molecular weight polyethylene fibers 图1.超高分子量聚乙烯纤维结构图 Fig 1.Model of UHMWPE Fiber fabricated from UHMWPE by the gel- spinning or melt-spinning processing 1.高结晶度（99%）,高取向度（99%） 2.线性非极性的亚甲基结构（-CH2-） 3.高度光滑的表面 表 面 粘 结 性 能 差 ---------------------------------------------------------------------------------------------------------------------------------------- Ackley M ,Gao P. Surface treatment of ult ra high molecular weight polyethylene to enhance adhesion and Conductivity properties [J ] . Polymer ,1992 ,33 : 19 2.Surface modification Via UV initiated Grafting Oster George Bengt Ranby 1957 acrylamide was grafted onto natural rubber via UV Irradiation for the first time by George Oster ; 1980s vinyl-monomers was grafted onto polymers via UV initiated grafting by Bengt Ranby ,and the photo initiator was the first time used in the surface modification of Polymers! 3. Surface modification Via UV initiated Grafting (2)Norrish Ⅱ (1)Norrish Ⅰ ---------------------------------------------------------------------------------------------------------------------------------------- Hageman HJ. In: Allen NS, editor. Photo-polymerisation and photoimaging science and technology. London: Elsevier Applied Science, 1989. p. 1. 3. Surface modif