Lattice enthalpy terms晶格焓术语.pptVIP

Born-Haber Cycles Introducing Lattice Enthalpies. Lesson objectives Define lattice enthalpy terms. Construct a simple Born Haber cycle. Relate MgO Lattice enthalpy to industrial use. Lattice enthalpy terms ?H? L.E = Lattice enthalpy. The standard enthalpy change when one mole of crystalline substance is formed from its constituent gaseous ions. Na+(g) + Cl-(g) → NaCl(S) Constructing a Born Haber Cycle for NaCl But how do we get -788kJ? Method 1 ?HatmNa +?HatmCl? +?HIE? +?H1stAE+ ?HL.E= ?Hformation Rearrange in terms of ?HL.E Gives ?HL.E= ?Hformation - (?HatmNa +?HatmCl? +?HIE? +?H1stAE)