油酸甘油酯的合成及其改善柴油润滑性研究.docVIP

油酸甘油酯的合成及其改善柴油润滑性研究 刘公召 马超 沈阳工业大学理学院 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 以对甲苯磺酸为催化剂, 甲苯为携水剂, 油酸和甘油为原料合成了二油酸甘油酯与三油酸甘油酯的混合物。实验考察了物质的量比、反应时间、反应温度和对甲苯磺酸 (催化剂) 用量对酯化率的影响, 并通过红外光谱对产品结构进行表征。结果表明, 适宜的反应条件是:n (丙三醇) ∶n (油酸) =0.7∶1;反应温度155160℃;反应时间9h;催化剂用量5%;甲苯 (携水剂) 用量20%, 在此条件下油酸的酯化率达99.4%, 产物的酸值 (mg·KOH/g) 2。用HFRR法评定产物抗磨性能, 结果表明:在低硫柴油中添加300mg/kg时, 磨斑直径从830μm降至386.6μm, 且不影响低硫柴油的其他理化性质。 关键词： 油酸甘油酯; 合成; 评定; 作者简介：刘公召 (1963-) , 男, 湖北省人, 博士, 教授, 主要研究方向为石油化工助剂, E-mail:liugongzhao666@163.com。 收稿日期：2016-11-22 Synthesis of Oleic Acid Glyceride and Its Research on Diesel Lubricity LIU Gong-zhao MA Chao School of Science, Shenyang University of Technology; Abstract： The mixture of two and three oleic acid glycerides was synthesized by using oleic acid and glycerol as raw materials, p-toluene sulfonic acid as catalyst, toluene as water carrying agent.The effects of reaction time, amount of the catalyst, reaction temperature and molar ratio of alcohol to acid on the esterification were investigated, and the product structure was characterized by IR spectrum.The experimental results show that a more than 99.4 percent of esterification rate can reached when the molar ratio of alcohol to acid is 0.7∶1, reaction temperature is 155160 ℃, reaction time is 9 h, the dosage of catalyst is 5% and the dosage of water carrying agent is 20%.The acid value of the product of esterification (mg·KOH/g) was less than 2.The antiwear properties of the product were evaluated by HFRR.The result showed that the wear scar diameter was decreased from 830μm to 386.6μm when 300 mg/kg was added into low sulfur diesel, and it does not affect the other physical and chemical properties of low sulfur diesel. Keyword： oleic acid glyceride; synthetic; evaluate; Received： 2016-11-22 为了更好地控制柴油车辆尾气排放, 对车用柴油硫含量提出了越来越严格的要求。我国在2013年对GB/T 19147《车用柴油》国家标准进行了修订, GB/T 19147—2013标准将车用柴油硫含量限值由“不大于50 mg/kg”加严至“不大于10 mg/kg”。清洁柴油标准的出台使得低硫柴油的需求量大大增加, 促进了柴油脱硫技术的发展, 目前各炼油厂的柴油脱硫主要采用