Formation of active radicals and mechanism of photocatalytic degradation of phenol process using eosin sensitized TiO2 under visible light irradiation研究.pdf

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Formation of active radicals and mechanism of photocatalytic degradation of phenol process using eosin sensitized TiO2 under visible light irradiation研究.pdf

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J．Cent．SouthUniv．(2013120：495—500 垒Springer DoI：10．1007／sl1771．013—1511．1 Formationofactiveradicalsandmechanism ofphotocatalyticdegradationof phenolprocessusingeosinsensitizedTi02undervisiblelightirradiation SONGLin(宋琳)一，ZHANGXin(张鑫)一，MAYun．kun(马云坤)一， LIMing—yu(~NZ)。一ZENGXiao．1ong(~sJ、龙1’ 1．DepartmentofEnvironmentalEngineering，JinanUniversity，Guangzhou510632，China； 2．KeyLaboratoryofW ater／SoilToxicPollutantsControlandBioremediation， DepartmentofEducationofGuangdongProvince，Guangzhou510632，China ◎CentralSouthUniversiytPressandSpringer—VerlagBerlinHeidelberg2013 Abstract：Theroleofoxygenandthegenerationofactiveradicalsinthephotocataliticdegradationofphenolwereinvestigatedusing theeosinsensitizedTiO，asphotocatalystundervisiblelightirradiation．Diffusereflectancespectrashow thattheabsorbancyrange ofeosin／TiO，isexpandedfrom378nnl(Ti0，1toabout600nm．Thephotocataliticdegradationofpheno¨salmoststoppedwhenthe eosiI1／Ti02system issaturatedwim N2，whichindicatesthesignificanceof0，．TheadditionofNaN (aquencherofsingleoxygen) causesabouta62％ decreaseinthephenoldegradation．Thepheno1degradationratioisdropped from 92％ to75％ when the isopropanolfaquencherofhydroxylradical1ispresentinthesystem．Theexperimentalresultsshow thattherearesingletoxygenand hydroxylradicalgenerated intheeosin／TiO，system undervisiblelightirradiation．Thechangesofabsorbancy indicatethatthe hydrogenperoxidemightbeproduced．Throughtheanalysisandcomparison，itisfoundthatthesingletoxygenisthepredominant activeradicalforthedegradationofpheno1． Keywords：eosinsensitizedTiO2；visiblelight；photocatalyticdegradation；reactionmechanism eosin／TiO7system havehardlybeen reported．Because 1IntrOductiOn