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石油学报(石油加工)
PETROI。EI
2008年10月 ACTA SINICA(PETROLEUMPR()CESSINGSECTION) 增刊
文章编号:1001-8719(2008)增刊一0338—04
HAT—plus重芳烃轻质化技术
祁晓岚,左 煜,陈雪梅,杨德琴,孔德金
(中国石化上海石油化工研究院,上海201208)
摘要:HAT—plus重芳烃轻质化工艺采以大孑L纳米分子筛为活性组分、非贵金属改性制备的催化剂,用于制备
苯、甲苯和二甲苯。该催化剂具有高活性、高选择性和高稳定性,重芳烃处理能力高于国外现有工艺催化剂。
稳定性实验结果表明,平均总转化率高于55%,BTX(苯、甲苯和二甲苯)总选择性大子75%,其中二甲苯选择
性可达60%。HAT—plus重芳烃轻质化技术可满足不同工况要求。
关键词:重芳烃;轻质化;催化剂;二甲苯
426,9
中图分类号:TQ241.1;TQ 文献标识码:A
FOR OFHEAVYAROMATICS
TECHNoLoGYCONVERSIoN
HAT-plus
ToLIGHTAROMATICS
QIXiao-lan,ZU0Yu,CHENXue-mei,YANG
De—qin,KONGDe-jin
(ShanghaiResearchInstitutePetrochemical Z01208,China)
of Technology,SINOPEC,Shanghai
to is of
Abstract:The forconversionof aromatics aromatics,whichconsisted
HAT—pluscatalyst heavy light
nanosizedmolecularsievewith andnon-noblemetals,canbeused benzene(B),
structure forproducing
largepore
toluene(T)and and
xylenes(X)fromC9 higheralkylaromatics.Thecatalystpresentedhighactivity。high
and maximumlimitof aromaticsinfeedstockswas thanother
selectivityhighstability.The CID higher representative
oversea of of to of showed
theconversionaromaticsaromatics.Theresults
technologies heavy light stabilitystudy
that totalconvertionof aromaticsexceeded55%andBTX was than75%,
average heavy averages
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