HATplus重芳烃轻质化技术研究.pdfVIP

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石油学报(石油加工) PETROI。EI 2008年10月 ACTA SINICA(PETROLEUMPR()CESSINGSECTION) 增刊 文章编号:1001-8719(2008)增刊一0338—04 HAT—plus重芳烃轻质化技术 祁晓岚,左 煜,陈雪梅,杨德琴,孔德金 (中国石化上海石油化工研究院,上海201208) 摘要:HAT—plus重芳烃轻质化工艺采以大孑L纳米分子筛为活性组分、非贵金属改性制备的催化剂,用于制备 苯、甲苯和二甲苯。该催化剂具有高活性、高选择性和高稳定性,重芳烃处理能力高于国外现有工艺催化剂。 稳定性实验结果表明,平均总转化率高于55%,BTX(苯、甲苯和二甲苯)总选择性大子75%,其中二甲苯选择 性可达60%。HAT—plus重芳烃轻质化技术可满足不同工况要求。 关键词:重芳烃;轻质化;催化剂;二甲苯 426,9 中图分类号:TQ241.1;TQ 文献标识码:A FOR OFHEAVYAROMATICS TECHNoLoGYCONVERSIoN HAT-plus ToLIGHTAROMATICS QIXiao-lan,ZU0Yu,CHENXue-mei,YANG De—qin,KONGDe-jin (ShanghaiResearchInstitutePetrochemical Z01208,China) of Technology,SINOPEC,Shanghai to is of Abstract:The forconversionof aromatics aromatics,whichconsisted HAT—pluscatalyst heavy light nanosizedmolecularsievewith andnon-noblemetals,canbeused benzene(B), structure forproducing largepore toluene(T)and and xylenes(X)fromC9 higheralkylaromatics.Thecatalystpresentedhighactivity。high and maximumlimitof aromaticsinfeedstockswas thanother selectivityhighstability.The CID higher representative oversea of of to of showed theconversionaromaticsaromatics.Theresults technologies heavy light stabilitystudy that totalconvertionof aromaticsexceeded55%andBTX was than75%, average heavy averages

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