氧化硅基底负载TiO2薄膜的制备及其光催化应用研究.docVIP

氧化硅基底负载Ti02薄膜的制备及其 光催化应用研究 北京化工大学理学院 以钛酸丁酯为钛源，乙酰丙酮和冰醋酸为水解抑制剂，聚乙二醇为致孔剂，制 备了一种稳定的1402水溶胶。采用浸渍提拉法将Ti02溶胶负载到活化的载玻片 上，再经180°C水热或500°C煅烧得到TiO2薄膜催化剂。采用扫描电子显微镜 (SEM)、原子力显微镜(AFM)、透射电子显微镜(TEM)、X射线晶体衍射(XRD) 和Raman光谱等分析手段对样品进行了表征，结果表明:门02薄膜是由粒径为8：2 nm的球形颗粒组成的多孔结构，其晶型为结品度良好的锐钛矿。以甲基橙为光 降解物，在紫外灯下测试薄膜的光催化性能，结果显示煅烧处理的Ti02薄膜催 化剂的光催化活性优于水热处理，对低浓度甲基橙的降解效率达90%以上，并 且多次重复使用后光催化活性基木保持不变。 关键词： Ti02薄膜;光催化;溶胶-凝胶法; 贺育敢男，1990年生，生 杨俊佼 E-mail:yangjj@mail. buct. edu. cn 2017-03-27 Fabrication of Ti02 films coated on a Si02 substrate and their application in photocatalysis HE YuGan ZHU MeiYing LONG Hao YANG JunJiao Faculty ofScience, Beijing University of Chemical Technology; Abstract： A very stable Ti02 hydrosol has been prepared via a facile sol-gel process using titanium butoxide and polyethylene glycol ( PEG) as a precursor and porogen respectively in the presence of acetylacetone and acetic acid. The Ti0 hydrosol was coated on a SiO2 substrate by a dip-coating method. Highly homogenous and transparent Ti02 films were fabricated by either a hydrothermal process at 180 °C or by calcination in the air at 500 °C. The films were characterized by XRD, Raman spectroscopy, SEM, TEM and AFM. The results showed that TiO2 films were the anatase phase, firmly coated on the SiO2 substrate, and mainly made up of nanoparti cl es with size in the range 8 12 nm. The photocatalytic degradation of methyl orange ( MO) in aqueous solution was carried out in order to evaluate the photocatalytic activity of the films. The results showed that the photocatalytic performance of TiO2 films prepared by annealing was better than those prepared by a hydrothermal process. The degradation ratio of MO under UV light irradiation reached 90% and did not change significantly when the catalyst was reused several times. Keyword： Ti02 film; photocatalysis; sol-gel method; Received： 2017-03-27 引言 Ti 02光催化剂由于具有性质稳定、价廉、无毒、无污染等优点而在光催化领域 得到广泛应用，如光催化储能、光催化降解有机污染物以及光催化杀菌等等，特 别是在光催化降解有机污染物方面的应用一直以来备受科研工作者关注UzZL 虽然Ti 02光催化剂有诸多优点，但因其粉体回收利用率低