_Ca_2SiO_4在不同水热条件下的水化作用_英文_.docxVIP

HYD RATIO N OFβ2D ICAL CI UM SIL ICATE UND ERD IFFERENT HYD ROTHERMAL CO ND ITIO NSH U Xi u2la n , K. Ya na gi sawa , A . O nda , K. Kajiyo shi( Resea rch L a bo rato r y of Hydro t her mal Chemi st r y , Facult y of Science , Kochi U niver sit y , Kochi 780 - 8520 , J ap a n)Abstract : Hydro t he r mal reactio n s of β2dicalci um silicat e synt he size d by soli d st at e reactio n we re ca r riedo ut i n st ai nle ss st eel a utocla ve s wit h a git atio n u nde r a n a uto ge no u s p re ssure by t wo diff ere nt hydro t her2mal t reat me nt met ho ds at t e mp erat ure s f ro m 150 ℃to 400 ℃ up to 5 day s. 7 ki nds of p ro duct s of calci umsilicat e hydrat e ( C2S2H) p ha se s wit h t he sa me C/ S ratio a s t he p recur so r (α2dicalci u m silicat e hydrat e a nd dellait e) , Ca2ric h co mpo sitio n (jaff eit e a nd rei nha r dbra u n sit e) , a nd Si2ric h co mpo sitio n ( C8 S5 , kil2 choa nit e a nd fo sha git e) , we re synt he size d f ro m β2dicalci um silicat e . The relatio n ship bet wee n t he o b2 t ai ned p ha se s a nd co nditio n s of fo r matio n , a nd t he st a bilit y a nd fo r matio n mecha ni sm of C2S2H p ha se we re di sc u ssed.Key words :hydratio n of β2dicalci um silicat e ; hydro t he r mal reactio n ; calci u m silicat e hydrat e ( C2S2H ) ;met a st a ble p ha se ; hi gh t e mp erat ure mi xi ng ; roo m t e mp e rat ure mi xi ngCL C Number :O782 + . 2Document Code : A0Introductionβ2dicalci u m silicat e i s o ne of t he mo st i mpo r t a nt co n stit ue nt s i n po r t la nd ce me nt . Ce me nt s u sed fo rca si ng geo t her mal well s o r deep oil2well s , a re e xpo se d to hi gh t e mp e rat ure s a nd p re ssure s. In geo t her2 mal well s , t he t e mp erat ure ca n be a s hi gh a s 400 ℃〔1〕. Hydratio n of β2dicalci um silicat e re sult s i n t he fo r matio n of calci um silicat e hydrat e s. Ma ny of re sea rc he r s〔2～6〕 have st udied t he met ho d ho w to i mp ro vehydratio n activit y of β2dica