[化学]南京大学结构化学双语课件CH7LEC2.pptVIP

7.3 Optical Spectra and Magnetics Topics: The Absorption Spectra Relation Between Absorbed and Observed Colors The Absorption Spectra Absorption spectra of typical transition metal complexes The Absorption Spectra The Absorption Spectra d2 configuration, assignment of absorption spectra The Absorption Spectra d2 configuration, assignment of absorption spectra The Spectrochemical Sequences The relative strength of ligands The Spectrochemical Sequences Example The High-Spin and Lower-Spin Magnetics The High-Spin and Lower-Spin Magnetics The High-Spin and Lower-Spin Magneton The High-Spin and Lower-Spin High-Spin and Low-Spin The High-Spin and Lower-Spin What is Epairing ? The High-Spin and Lower-Spin What is Epairing ? The High-Spin and Lower-Spin What is Epairing ? The High-Spin and Lower-Spin What is Epairing? The High-Spin and Lower-Spin The High-Spin and Lower-Spin The High-Spin and Lower-Spin Example 7.4 Stereochemistry Lower Coordinations Lower Coordinations Symmetry of Five-Coordinate Complexes Lower Coordinations Symmetry of Four-Coordinate Complexes Lower Coordinations Four-Coordinate Complexes Jahn-Teller Distortion Definition Jahn-Teller Distortion Example Jahn-Teller Distortion Distortion of Octahedral Complexes Distortion of Octahedral Complexes Jahn-Teller Distortion Distortion of Octahedral Complexes 7.5 Molecular Orbital Theory s bonding 7.5 Molecular Orbital Theory s bonding 7.5 Molecular Orbital Theory Energy Level Diagram x y z For systems in which the ligands and the central atom have strong covalent interactions, the crystal field theory fails to explain the charge-transfer absorption bands, MO theory description is needed. Fe(CO)5 s bonding Fe(C5H5)2 p bonding Examples: 1 2 3 4 5 6 Symmetry Adapted Linear Combinations dxy dyz dzx t2g N.A. dxy dyz dzx eg dx2-y2 dz2 a1g t1u s px py pz MO symmetry SALC of the ligands Central Atom * * * /notes/ch7lec2.ppt The absorption spectra The spectrochemical Sequences High-spin and Low-spi