Synthesis of inorganic nano-hollow spheres by surface reaction and deposition-材料合成化学课件PPT.pptVIP

Silicon carbide hollow nano-spheres Materials:SiCl4 C6Cl6 and Na Chemical Physics Letters Volume 375, Issues 1-2 Other hollow non-oxide spheres Materials:NH4BF4 and KBH4 with zinc Boron nitride hollow spherel CHEMICAL PHYSICS LETTERS 381 (1-2): Materials Letters Volume 60, Issue 20 ZnS micrometer hollow spheres N2 SO2 Zn(NO3)2·2H2O and Na2S2O3·2H2O Gas! The gas maybe is the reason of the hollow spheres. Solvent-thermal Synthesis Focus of current research Preparation of non-oxide hollow spheres with combined template technology and polymer precursors (Si-N-B) Preparation of ZnO hollow spheres and its photoluminescence research The assembly of nano-hollow spheres and their application in various field. Nobel prize 2005 Yves chauvin Rober H Grubbs Richard R Schrock ROMP(ring-opening metathesis polymerization ) J. Am. Chem. Soc. 1999, 121, 462-463 Au Ru=C Grubbs initiator ROMP:A development of SCRD method Synthesis of inorganic nano-hollow spheres by surface reaction and deposition Outline Fundamental concepts General synthesis method of core-shell particles Surface chemical reaction and deposition (Hollow oxide, nitride, carbide, boride spheres) Focus of current research What is a core-shell structure? Consist of either organic or inorganic core and coated with shells Selective dissolution or calcinations to obtain a hollow sphere What special properties could be observed? Different surface chemical composition Increased stability Higher surface area Magnetic and optical properties Fundamental concepts What is it for? Due to its special structure and attractive functional features, it could be used in: Catalysis, coatings Capsule agent for drug delivery Protection for sensitive agent (enzyme..) Electro-optic crystal And so on…. Fundamental concepts Synthesis methods Chemical methods Template method Template and layer-by-layer method(LBL) Surface chemical reaction and deposition(SCRD) Kirkendall effect Temp