Synthesis of Magnetic Iron Oxide Nanoparticles Fe3O4-材料合成化学课件PPT.pptVIP

Synthesis of Magnetic Iron Oxide Nanoparticles Outline Introduction Synthesis methods Applications Focus of Current Research Reference Introduction Application Magnetic storage media Biosensing applications Medical applications MRI Magnetic inks for printing Synthesis methods Classical Synthesis by Coprecipitation Pyrolysis Oleic acid Iron Hydrothermal and High-Temperature Reactions Sol-Gel Reactions Flow Injection Synthesis Electrochemical Methods Aerosol/Vapor Methods Sonolysis Method(1)：Coprecipitation Chemical Reaction: Fe2++2Fe3++8OH- Fe3O4+4H2O Reaction condition: pH: 8~14 Fe3+/Fe2+: 2:1 or 3:2 Environment: non-oxidation Equipment Process Influence Factor Reaction Temperature Addition Manner Alkali Source pH Malysite solution Surface Active Agent Mixing Methode Alkali Source Protection Inorganic Component: Silica, Gold, Carbon Organic shells: Dextran, PEG, PVA, Alginate, Chitosan, Other Polymers, Carboxylates, Phosphates Other Strategies for Protection Organic Stabilizers Advantage and Disadvantage Advantage: Large amount of nanoparticles can be synthesized. Disadvantage: Relatively poor size uniformity; Low crystallinity; Toxicity. Method(2)：Pyrolysis oleic acid iron Steps 1.Nucleation occurs at 200-240℃ triggered by the dissociation of one oleate ligand from the Fe(oleate)3 precursor by CO2 elimination; 2. The major growth occurs at ~300℃ initiated by the dissociation of the remaining two oleate ligands from the iron oleate species, although slow growth seems to occur at 250℃. Influence Factor Reaction Temperature Reaction Time Aging period Different solvents Advantage Monodisperse; Ultra-large Scale; Better crystallinity; Environmentally Friendly Economical Focus of Current Research Simple Process and Low Cost High Crystallinity Good Magnetic Properties Well Dispersed Size Stable Reference Sophie Laurent, Delphine Forge, Marc Port et al. Mag